Flame retardant and antistatic polyoxymethylene resin based on compound halogen-free flame retardant system

A polyoxymethylene resin, flame retardant and antistatic technology, applied in the field of polyoxymethylene resin preparation, can solve the problems of single performance of flame retardant polyoxymethylene and antistatic polyoxymethylene, and achieve good thermal stability and mechanical properties

Inactive Publication Date: 2015-10-07
河南能源集团研究总院有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem to be solved by the present invention is that the flame-retardant polyoxymethylene and antistatic polyoxymethylene in the prior art have single performance and cannot meet the technical defects of some special application fields, and provide a kind of polyoxymethylene with both flame-retardant and antistatic properties. Polyoxymethylene resin preparation method

Method used

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  • Flame retardant and antistatic polyoxymethylene resin based on compound halogen-free flame retardant system

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] The weight ratio of 64% POM, 10% red phosphorus microcapsules, 2% triphenyl phosphate, 4% melamine, 5% phenolic resin, 14% conductive carbon black, 0.2% silicon dioxide, 0.3% antioxidant 245 and 0.5 % Lithium stearate was premixed on a high-speed mixer for 10 minutes, then melted and extruded in a twin-screw extruder at 165-175°C to granulate, and then injection-molded on an injection molding machine.

Embodiment 2

[0031] The weight ratio of 62% POM, 10% red phosphorus microcapsules, 2% RDP, 4% melamine, 5% phenolic resin, 16% conductive carbon black, 0.2% silicon dioxide, 0.3% antioxidant 245 and 0.5% polyethylene The diol is pre-mixed on a high-speed mixer for 10 minutes, and then melted and extruded at 165-175°C in a twin-screw extruder to make pellets, and then injection-molded on an injection molding machine.

Embodiment 3

[0033] Put 64.3% POM, 10% red phosphorus microcapsules, 4% melamine, 5% phenolic resin, 14% conductive carbon black, 0.2% aluminum oxide, 0.3% antioxidant 1010 and 2% polyethylene wax on a high-speed mixer Pre-mixed for 10 minutes, then melt-extruded and granulated in a twin-screw extruder at 165-175°C. Then the extruded particles were dried at 105° C. and mixed in a kneader for 2 minutes, and then injection-molded on an injection molding machine.

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Abstract

The invention discloses flame-retardant anti-static polyformaldehyde resin. The flame-retardant anti-static polyformaldehyde resin is prepared from the following raw materials in percentage by weight: 45-80 percent of polyformaldehyde (POM), 5-35 percent of compound halogen-free flame retardant, 3-20 percent of charring agent, 1-15 percent of formaldehyde absorbent, 0.1-5 percent of flame retardant synergist, 1-30 percent of antistatic agent, 0.1-5.0 percent of processing aid and 0.1-3.0 percent of antioxidant. The flame retardant anti-static polyformaldehyde resin is prepared by adopting the following steps of: premixing POM, the compound halogen-free flame retardant, the charring agent, the formaldehyde absorbent, the flame retardant synergist, the antistatic agent, the processing aid and the antioxidant in a high-speed mixer for 3-15min, then performing melt extrusion and granulation on the mixed raw materials in a twin-screw extruder, and performing injection molding on an injection molding machine. A polyformaldehyde composite material prepared by adopting the flame-retardant anti-static polyformaldehyde resin has flame retardance property and anti-static property, and better thermal stability property and mechanical property, and can meet the demand of multiple application environments for polymer products underground a coal mine.

Description

technical field [0001] The invention relates to a method for simultaneously improving the flame-retardant performance and antistatic performance of a base material, and preparing a polyoxymethylene resin with dual functions of flame retardancy and antistatic. Background technique [0002] Polyoxymethylene (POM) is a highly crystalline linear polymer with an extremely regular molecular structure, a high degree of crystallization, and excellent physical properties. It has high elastic modulus, hardness and rigidity, good creep resistance, fatigue resistance and friction resistance, and also has self-lubricating characteristics. Its specific rigidity and specific strength are close to those of metals, its tensile strength, bending strength and fatigue resistance are excellent, its friction coefficient is small, and its dimensional stability is high. It can be used as a substitute for some metal materials. It is often used to replace non-ferrous metals to make buttons, gears, v...

Claims

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Application Information

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Patent Type & AuthorityPatents(China)
IPC IPC(8): C08L59/00C08K13/06C08K9/10C08K3/02C08K5/523C08K5/3492C08K3/32
Inventor房晓敏付瑶丁涛吴保章徐元清魏灵朝龚春红田一政张璞赵利军张延兵宋灿吴俊威曹志魁金璐李建通任艳蓉
Owner河南能源集团研究总院有限公司