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A kind of coated iron electrode and preparation method thereof

An iron electrode, coating technology, applied in battery electrodes, alkaline battery electrodes, circuits, etc., can solve the problems of large distance between active material and current collector steel belt, low utilization rate of active material, weak high current discharge capacity, etc. , to achieve the effect of strengthening the high-current discharge capacity, satisfying high-rate discharge, and improving the high-current discharge capacity

Active Publication Date: 2016-08-24
河南创力新能源科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

According to capacity requirements, the required number of plate strips are spliced ​​together by mechanical force, and then cut into plate blanks of different widths according to the required size, and then the blanks are put into the plate frame, and the plate is formed by embossing , and finally weld or assemble the plate on the collector plate to form a complete iron electrode, but the manufacturing process of this bag-type iron electrode is complicated, and the equipment investment is large. Low, high current discharge capacity is weak, generally only suitable for making iron-nickel batteries with medium and low rate discharge (current discharge below 1C rate)

Method used

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  • A kind of coated iron electrode and preparation method thereof
  • A kind of coated iron electrode and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Preparation of coated iron electrodes

[0017] (1) Preparation of active material mixture: mix 87g of reduced iron powder, 5g of additive nickel sulfate and 7g of conductive graphite, and then add 5g of binder aqueous solution with a mass concentration of 20% prepared by 1g of binder to prepare Stir and mix evenly to make the active material mixture; (2) Preparation of foamed nickel matrix or foamed iron matrix: After the foamed sponge is electroplated with nickel, the foamed nickel matrix is ​​obtained by burning the sponge, and the foamed sponge is subjected to After electroplating iron and then electroplating nickel, the foamed iron matrix is ​​obtained by burning off the sponge; (3) Forming of the coated iron electrode: brushing the active material mixture prepared in step (1) on the hair foam prepared in step (2) In the foamed nickel matrix or the foamed iron matrix, the pole plate 1 is obtained by pressing, punching, and spot welding the tabs, and then wrapping th...

Embodiment 2

[0027] Preparation of coated iron electrodes

[0028] (1) Preparation of active material mixture: uniformly mix 91.3g of reduced iron powder, 3g of additive nickel hydroxide and 5g of conductive agent acetylene black, and then add 0.7g of binder to prepare a binder aqueous solution with a mass concentration of 14%. 5g, and stir evenly, to make the active material mixture; (2) Preparation of foamed nickel matrix or foamed iron matrix: the foamed nickel matrix is ​​obtained by burning the foamed sponge after electroplating nickel, and the foamed After the sponge is electroplated with iron and then electroplated with nickel, the foamed iron matrix is ​​obtained by burning the sponge; (3) Forming of the coated iron electrode: brushing the active material mixture prepared in step (1) on the prepared In the foamed nickel matrix or foamed iron matrix, the plate is made by pressing, punching, and spot welding the tabs, and then the braided mesh is wrapped on both sides of the plate an...

Embodiment 3

[0038] Preparation of coated iron electrodes

[0039] (1) Preparation of active material mixture: uniformly mix 95.5g of reduced iron powder, 1g of additive titanium dioxide and yttrium oxide mixture, and 3g of conductive agent graphite, and then add 0.5g of binder to prepare a binder with a mass concentration of 10%. Preparation of 5 g of aqueous solution of the agent, stirring evenly, and then making the active material mixture; (2) Preparation of foamed nickel matrix or foamed iron matrix: After the foamed sponge is electroplated with nickel, the sponge is burned to obtain a foamed nickel matrix. The foamed sponge is electroplated with iron and then electroplated with nickel, and then the sponge is burned to obtain a foamed iron matrix; (3) Forming of the coated iron electrode: brush the active material mixture prepared in step (1) on step (2) Forming of coated iron electrodes: Brush the active material mixture prepared in step (1) on the foamed nickel matrix or foamed iron...

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Abstract

The invention discloses a coated iron electrode and a preparation method thereof. The gist of the technical solution of the present invention is: a coated iron electrode, including a pole plate, the pole plate is mainly composed of a foamed nickel matrix or a foamed iron matrix and an active active material coated in the foamed nickel matrix or foamed iron matrix. Composed of materials, the two sides of the pole plate are respectively coated with cut-and-pull mesh, punched mesh belt, woven mesh or microporous metal sheet, and the cut-and-drawn mesh, punched mesh belt, woven mesh or microporous metal sheet is mechanically After rolling or seam welding or mechanical rolling and seam welding, the electrode plate is wrapped in a cut mesh, punched mesh belt, woven mesh or microporous metal sheet. The invention also discloses a preparation method of the coated iron electrode. Compared with the traditional bag-type iron electrode, the coated iron electrode of the present invention has an active material utilization rate increased by 28%-30%, and a high-current discharge capacity increased by 50%-60%.

Description

technical field [0001] The invention belongs to the technical field of secondary batteries, and in particular relates to a coated iron electrode and a preparation method thereof. Background technique [0002] At the end of the 19th century and the beginning of the 20th century, JUNJER in Europe and EDISON in the United States invented the iron-nickel battery, which is a secondary battery with an iron electrode as the negative electrode and nickel oxyhydroxide as the positive electrode. Because the iron electrode can withstand overcharge and overdischarge, long-term discharge state shelving and other electrical performance abuse, and the iron electrode has a long service life, the cycle life can reach more than 2000 times, and the service life is more than 20 years, and because the iron electrode uses iron as the Active materials, compared with cadmium-nickel batteries, cadmium and lead materials used in the negative electrode of lead-acid batteries, do not constitute environ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M10/30H01M4/24H01M4/32
CPCH01M4/248H01M4/32H01M10/30Y02E60/10
Inventor 杨玉锋李群杰李喜歌
Owner 河南创力新能源科技股份有限公司