SOI wafer manufacturing method
A manufacturing method and wafer technology, applied in chemical instruments and methods, semiconductor/solid-state device manufacturing, crystal growth, etc., to achieve the effect of reducing costs and suppressing HF defects
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Embodiment 1
[0072] (Example 1, Comparative Examples 1-3)
[0073] Demonstration of the effect of resistance heat treatment
[0074] For a silicon wafer with a diameter of 200 mm, N-region (NPC), and an initial oxygen concentration of 12 ppma, no pretreatment (condition 1), RTA (condition 2), resistance heating treatment (condition 3) or resistance heating treatment + grinding After (Condition 4), (1) perform oxidation heat treatment at 900°C / 6hrs, (2) remove the oxide film with HF (simulated peeling), and (3) measure HF on the surface of 65 nm or more with SP1 manufactured by KLA-Tencor Defect density, (4) After grinding 5 μm, the above steps are set as the 0th regeneration number, and further repeating (1) to (4) to simulate the process of reusing the bonded wafer, and the HF defect density according to the regeneration number Compare. The result is expressed in figure 2 middle.
[0075] In addition, "simulated peeling" in (2) refers to replacing the peeling process (attachment to...
Embodiment 2
[0087] Verification of the effect due to the difference in the initial oxygen concentration between nitrogen-doped wafers and NPC wafers
[0088] For a diameter of 200mm and a nitrogen concentration of 5×10 13 atoms / cm 3 , a wafer with an initial oxygen concentration of 3-17ppma, and a wafer with a diameter of 200mm, an N-region (NPC), and an initial oxygen concentration of 3-17ppma, heat treatment at 1200°C for 60 minutes in an oxygen atmosphere, and then, with In Example 1, the simulated regeneration method was repeated five times to measure the HF defect density. The result is expressed in image 3 middle.
[0089] As a result, HF defects were not problematic in any of the wafers. Among them, when the initial oxygen concentration of the nitrogen-doped wafer is below 7ppma, and the initial oxygen concentration of the NPC wafer is below 14ppma, almost no HF defects are detected.
Embodiment 3
[0091] Fabrication of SOI Wafers 1
[0092] As a bonded wafer, prepare a mirror-polished silicon wafer with a diameter of 200 mm, an N-region (NPC), and an initial oxygen concentration of 12 ppma, and perform a process for eliminating defects of the bonded wafer at 1200° C. for 60 minutes in an oxygen atmosphere. After the heat treatment, etching was performed with HF to remove the oxide film, and the surface to be bonded was polished to 0.1 μm. Next, (i) after performing an oxidation heat treatment at 900°C / 6hrs to form an oxide film, (ii) implant hydrogen ions through the oxide film (implantation conditions are: acceleration energy is 70keV, implantation amount is 6×10 16 / cm 2 ), (iii) after bonding the ion-implanted bonded wafer to the base wafer (silicon wafer) at room temperature, the ion-implanted layer is peeled off by applying a peeling heat treatment at 500° C. for 30 minutes, Fabricate SOI wafers.
[0093] At this time, a peeled wafer separated from the SOI waf...
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