Transparent note sheet and method for manufacturing same
A sheet and note technology, which is applied to chemical instruments and methods, container of unadhered notepad-like single sheets, identification devices, etc., can solve problems such as difficult adjustment of fine protrusions, and achieve excellent writability , the effect of low haze
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[0122] The present invention will be further explained with reference to the following illustrative examples and comparative examples of the present invention.
[0123] Examples 1 to 24
[0124] In Examples 1 to 24, primer-treated polyethylene terephthalate (PET) film (MELINEX TM 618, available from U.S. DuPont Teijin Film Co., Ltd.) as a substrate to make the note of the present invention, the film has a width of about 9 inches (22.86 cm) and a thickness of about 5 thousandths of an inch (0.127 mm). Used as a resin substrate.
[0125]As shown in Table 1, the coating layer precursor was made of a commercially available UV-curable acrylic resin hardcoat material (906 Hardcoat, manufactured by 3M), which can be Used alone or mixed in a blend of propoxylated (2) neopentyl glycol diacrylate (SR9003, manufactured by Sartomer, LLC).
[0126] Use with Figure 5 In the continuous manufacturing system configured in the manufacturing system system shown in , the resin coating lay...
example 4
[0143] A photomicrograph of the fine relief structure of the front surface of the Example 4 note sheet is in Figure 11 shown in .
[0144] For each of Examples 1 to 24, manufacturing conditions (composition ratio of coating material, film thickness of coating layer precursor), unevenness formation evaluation (surface roughness and distance between adjacent peaks), optical characteristics (transmittance and haze), and writability are shown in Table 1.
example 1
[0145] The optical properties of the note sheet of Example 1 and a commercially available film-type marker used in Comparative Example are shown in Table 2.
[0146] Haze values and values (R a / NNp) in Figure 12 shown in . Also, writability and value (R a / NNp) in Figure 13 shown in .
[0147]
[0148] [Table 2]
[0149] sample
Haze (%)
Example 1
29.9
94.0
Comparative example 1
85.16
79.18
Comparative example 2
77.67
97.01
Comparative example 3
66.80
96.40
[0150] Examples 25 to 41
[0151] In Example 25, the primer-treated PET film (MELINEX TM 618, commercially available from DuPont Teijin Films, USA) was used as the substrate, the film having a width of about 9 inches (22.86 cm) and a thickness of about two thousandths of an inch (0.0508 mm). In addition, a commercially available ultraviolet-curable acrylic resin hard coat material (906HC, manufactured...
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