A kind of sn1-0.5xcuxs2 nano flower and its preparation and application

A technology of nanoflowers and nanosheets, applied in other chemical processes, chemical instruments and methods, physical/chemical process catalysts, etc., can solve the problems of complex preparation process and poor performance of finished products, and achieve high carrier mobility, Good prospects for industrialization promotion, and the effect of simple reaction and operation

Active Publication Date: 2018-07-31
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the above-mentioned method either has problems such as complex preparation process or poor performance of the finished product.

Method used

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  • A kind of sn1-0.5xcuxs2 nano flower and its preparation and application
  • A kind of sn1-0.5xcuxs2 nano flower and its preparation and application
  • A kind of sn1-0.5xcuxs2 nano flower and its preparation and application

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Add 2.488mmol crystalline tin tetrachloride (SnCl 4 ·5H 2 O), 0.0249mmol copper chloride dihydrate (CuCl 2 2H 2 O), 5mmol thioacetamide (CH 3 CSNH 2 ) and 30mL ethanol, stir until the solution is clear, take out the stirring bar, put the inner liner into the reaction kettle, keep it in a constant temperature oven at 180°C for 12h, stop heating, cool to room temperature in the oven, centrifuge, and use deionized water After washing with ethanol three times each, dry in a constant temperature drying oven at 60°C to obtain a product marked as Sn 1-0.5x Cu x S 2 -1, (x=0.01) was used for subsequent analysis. The diameter of the product nanoflower is about 3μm, and the specific surface area is 68㎡ / g.

Embodiment 2

[0040] Add 2.2 mmol of crystalline tin tetrachloride (SnCl 4 ·5H 2 O), 0.56mmol copper chloride dihydrate (CuCl 2 2H 2 O), 5mmol thioacetamide (CH 3 CSNH 2 ) and 30mL ethanol, stir until the solution is clear, take out the stirring bar, put the inner liner into the reaction kettle, keep it in a constant temperature oven at 180°C for 12h, stop heating, cool to room temperature in the oven, centrifuge, and use deionized water After washing with ethanol three times each, dry in a constant temperature drying oven at 60°C to obtain a product marked as Sn 1-0.5x Cu x S 2 -2, (x=0.25) was used for subsequent analysis and characterization. The diameter of the product nanoflower is about 5μm, and the specific surface area is 70㎡ / g.

Embodiment 3

[0042] Add 2.25 mmol crystalline tin tetrachloride (SnCl 4 ·5H 2 O), 0.5mmol copper chloride dihydrate (CuCl 2 2H 2 O), 5mmol thioacetamide (CH 3 CSNH 2 ) and 30mL of ethanol, put in a stirrer and stir until the solution is clear, take out the stirrer, put the lining in the reaction kettle and keep it in a constant temperature oven at 180°C for 12h. After stopping the heating, cool it to room temperature in the oven, centrifuge, and After washing with deionized water and ethanol three times respectively, dry in a constant temperature drying oven to obtain the product Sn 1-0.5x Cu x S 2 -3, (x=0.2) was used for subsequent analysis and characterization. The diameter of the product nanoflower is about 3μm, and the specific surface area is 73.45㎡ / g.

[0043] The sample Sn 1-0.5x Cu x S 2 -1, Sn 1-0.5x Cu x S 2 -2 and Sn 1-0.5x Cu x S 2 -3 Use scanning electron microscopy (SEM) to characterize the morphology, size, etc. of the prepared samples, the results are as f...

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Abstract

The invention relates to a Sn1‑0.5xCuxS2 nano flower and its preparation and application; it belongs to the technical field of design and preparation of special nano materials. The chemical formula of the nanoflowers of the present invention is Sn1-0.5xCuxS2, wherein the value of x is 0.01-0.25. The nanoflowers are composed of Sn1‑0.5xCuxS2 nanosheets through mutual mosaic or interpenetration. Its diameter is 1-5μm, and its specific surface area is 63-83㎡ / g. The preparation method is as follows: after dispensing Sn source, Cu source and S source according to the designed composition, add the prepared Sn source, Cu source and S source into the solvent and mix evenly to obtain a mixed solution, and then place the mixed solution in the reaction React in a kettle at 160-200°C to obtain Sn1-0.5xCuxS2 nanoflowers. The Sn1‑0.5xCuxS2 nanoflowers designed in the present invention can be used to catalyze the decomposition of organic matter. The invention has reasonable component design, simple preparation process, excellent and stable performance of the obtained product, and is convenient for large-scale industrial application.

Description

technical field [0001] The present invention relates to a kind of Sn 1-0.5x Cu x S 2 Nanoflowers and their preparation and application; belong to the technical field of design and preparation of special nanomaterials. Background technique [0002] With the rapid economic growth, energy shortage and environmental pollution have become two major problems plaguing mankind. If the energy shortage is not solved, the development and progress of human beings will be hindered; if the environmental pollution is not solved, the survival of human beings will be in jeopardy. Therefore, countries around the world have invested huge manpower and material resources in the hope of changing this predicament. Solar energy is one of the energy sources with abundant reserves. Semiconductor photocatalytic materials can convert solar energy into chemical energy and degrade organic or heavy metal pollutants. Semiconductor photocatalytic materials have been extensively studied. [0003] In ter...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J27/04B01J20/02B01J20/28B01J20/30C02F1/30
CPCY02W10/37
Inventor 潘军马永进陈熹谭鹏飞吴函朔
Owner CENT SOUTH UNIV
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