A kind of synergist for hair dyeing and its preparation and application
A synergist and acid-binding agent technology, applied in the field of synergists for hair dyeing, can solve the problems of formula application hindrance, unpleasant smell, etc., achieve permanent hair dyeing effect, avoid unpleasant smell, and novel structure
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Embodiment 1
[0036] At room temperature, dissolve 14.3g (0.1mol) of sodium cysteine in 100ml of water, cool it below 0°C with an ice-water bath, add dropwise 12.4g (0.11mol) of chloroacetyl chloride, and dropwise add a mass fraction of 17.6% 30ml of sodium carbonate solution (0.05mol), maintain the pH between 7-8, dropwise for about 30min, after the dropwise addition, stir and react for 3h, then warm up to room temperature, gradually add thiourea 7.6g (0.1mol), After 10 min of addition, continue stirring for 12 h, filter the precipitated white solid powder, wash with 100 ml of water, and dry to obtain 21.2 g of 2-[2-(thioureido)acetamido]-3-mercaptopropionic acid, yield 89.4% . 1H-NMR (400MHz, CDCl 3 )δ:1.5(1H,s),2.93-3.18(2H,m),3.76(2H,m),4.78(1H,m),8.32(1H,s),9.27-9.29(3H,m),12.57 (1H,s).
[0037] Weigh 23.6g (0.1mol) of 2-[2-(thioureido)acetamido]-3-mercaptopropionic acid, add 200ml of water, and add 17.1g (0.1mol) of barium hydroxide, heat to 50-60°C , hydrolyzed for 3h, and then...
Embodiment 2
[0039] Dissolve 143g (1mol) sodium cysteine in 1L of water, cool to 0-5°C with an ice-water bath, add dropwise 271g (1.2mol) chloroacetyl chloride, and simultaneously add dropwise 300ml of sodium carbonate solution with a mass fraction of 17.6% ( 0.5mol), keep the pH between 7-8, the dropwise addition time is about 5h, stir the reaction for 3h after the dropwise addition is completed, then warm up to room temperature, gradually add thiourea 91.2g (1.2mol), 2h after adding, continue to stir After 12 hours, the precipitated white solid powder was filtered, washed with 1 L of water, and dried to obtain 215.7 g of 2-[2-(thioureido)acetamido]-3-mercaptopropionic acid, with a yield of 91%. 1H-NMR (400MHz, CDCl 3 )δ:1.5(1H,s),2.93-3.18(2H,m),3.76(2H,m),4.78(1H,m),8.32(1H,s),9.27-9.29(3H,m),12.57 (1H,s).
[0040] Weigh 236g (1mol) of 2-[2-(thioureido)acetamido]-3-mercaptopropionic acid, add 2L of water, and add 171g (1mol) of barium hydroxide, heat to 60-70°C, hydrolyze for 4h, A...
Embodiment 3
[0052] Formulate the synergist and dye according to the following table (see Table 3) to obtain the corresponding hair dye.
[0053] table 3
[0054]
[0055]
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