Adhesive composition and bonding method using the same
A technology of adhesives and compositions, applied in the directions of bonding methods, types of adhesives, starch adhesives, etc., can solve problems such as air pollution and loss of raw materials, and achieve the effect of saving curing conditions
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preparation example 1
[0070] Preparation Example 1: Preparation of Urea-Formaldehyde Resin 1
[0071] 340 g of formaldehyde (Formalin: Formaline (37%)) and 126 g of urea (Urea) were added to a 4-necked synthesis flask equipped with a thermometer and a stirring device, and stirred at room temperature while blowing nitrogen gas. Then, after confirming that the liquid phase was clear, 0.8 g of sodium hydroxide (20% aqueous solution) was added. Then, after confirming that the pH reached the level of 8-9, the temperature was gradually raised to 80°C. After maintaining at this temperature for 2 hours, the temperature was lowered to room temperature, and then diluted with 232 g of distilled water. As a result, a urea-formaldehyde resin having a solid content of 36% and a pH of 8.26 was obtained. Here, it was confirmed that the total molar equivalent ratio of formaldehyde to the urea (Urea) was 2:1.
preparation example 2
[0072] Preparation Example 2: Preparation of Urea-Formaldehyde Resin 2
[0073] 511 g of formaldehyde (formalin (37%)) and 126 g of urea (Urea) were added to a 4-neck synthesis flask equipped with a thermometer and a stirring device, and stirred at room temperature while blowing nitrogen gas. Then, after confirming that the liquid phase was clean, 1.0 g of sodium hydroxide (20% aqueous solution) was added. Then, after confirming that the pH reached the level of 8-9, the temperature was gradually raised to 80°C. After maintaining at this temperature for 2 hours, the temperature was lowered to room temperature, and then diluted with 238 g of distilled water. As a result, a urea-formaldehyde resin having a solid content of 36% and a pH of 8.31 was obtained. Here, it was confirmed that the total molar equivalent ratio of formaldehyde to the urea was 3:1.
Embodiment 1
[0075] Add 350kg, the urea-formaldehyde resin composition that makes in the preparation example 1, the molasses (Molasses (80%) of 310kg, the citric acid (Citric acid (98%)) of 30kg, the distilled water of 3800kg, 2kg Silicone waterproofing agent (SI1420Z-KCC) and 3kg of dustproof oil (Dust Oil-Govi Garo217S) were stirred with a mixer for 30 minutes to prepare an adhesive composition. It was confirmed that the solid content of the prepared adhesive was about 9%.
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