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A kind of silver-loaded expanded graphite prepared from extra large flake graphite and its preparation and application

A technology of expanded graphite and flake graphite, which is applied in the field of materials, can solve the problems that expanded graphite particles are easy to fall off and affect the use effect, and achieve the effect of low cost, good use effect and avoiding bacterial infection

Active Publication Date: 2020-08-04
TSINGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Patent CN951155437.0 uses ordinary large flake graphite (particle size ≤ 0.5mm) to prepare the dressing. Due to the small particle size, when the flake dressing is used, the expanded graphite particles are easy to fall off, which affects the use effect

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A preparation method of silver-loaded expanded graphite prepared from extra-large flake graphite, utilizing the impregnation reduction method, comprising the following steps

[0030] Step 1, using extra large flake graphite as raw material, adopting a chemical oxidation method to obtain expandable graphite.

[0031] Step 2, under magnetic stirring, in silver nitrate solution (silver nitrate concentration is 0.02mol / L), slowly add the ammoniacal liquor that mass fraction is 10%, after the precipitate that produces is dissolved, configure silver ammonia solution, take 0.5g can be Put expanded graphite into 70mL silver ammonia solution and stir at room temperature for 30min, add dropwise 7mL (concentration: 0.2mol / L) of glucose solution, continue to stir at room temperature for 3h, wash with ultrapure water until the filtrate does not contain silver, then filter, and then place in 100 ℃ oven for 2 hours to obtain silver-loaded expandable graphite.

[0032] Step 3, rapid e...

Embodiment 2

[0035] A preparation method of silver-loaded expanded graphite prepared from extra-large flake graphite, utilizing the impregnation reduction method, comprising the following steps

[0036] Step 1, using extra large flake graphite as raw material, adopting a chemical oxidation method to obtain expandable graphite.

[0037] Step 2, under magnetic stirring, in silver nitrate solution (silver nitrate concentration is 0.005mol / L), slowly add the ammoniacal liquor that mass fraction is 10%, after the precipitate that produces is dissolved, configure silver ammonia solution, take 0.5g can Put expanded graphite into 70mL silver ammonia solution and stir at room temperature for 30min, add dropwise 2mL (concentration: 0.2mol / L) of glucose solution, continue to stir at room temperature for 3h, wash with ultrapure water until the filtrate does not contain silver, filter, and then place in 100 ℃ oven for 2 hours to obtain silver-loaded expandable graphite.

[0038] Step 3, rapid expansio...

Embodiment 3

[0041] A preparation method of silver-loaded expanded graphite prepared from extra-large flake graphite, utilizing the impregnation reduction method, comprising the following steps

[0042] Step 1, using extra large flake graphite as raw material, adopting a chemical oxidation method to obtain expandable graphite.

[0043] Step 2, under magnetic stirring, in silver nitrate solution (silver nitrate concentration is 0.00125mol / L), slowly add the ammoniacal liquor that mass fraction is 10%, after the precipitate that produces is dissolved, configure silver-ammonia solution, take 0.5g can be Put expanded graphite into 70mL silver ammonia solution and stir at room temperature for 30min, add dropwise 500μL (concentration: 0.2mol / L) of glucose solution, continue to stir at room temperature for 4h, wash with ultrapure water until the filtrate does not contain silver, filter, and then place in 100 ℃ oven for 2 hours to obtain silver-loaded expandable graphite.

[0044] In step three, ...

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Abstract

The invention discloses silver-loaded expanded graphite prepared by extra-large flaky graphite and preparation and application thereof. The expanded graphite is loaded with silver nanoparticles, and is prepared by the extra-large flaky graphite. Specific methods comprise an impregnating reducing method, a coating method and a spraying method; the impregnating reducing method adopts a non-toxic reducing agent to simultaneously reduce oxygen-containing functional groups and silver ions of the graphite; the coating method refers to coat a layer of silver nitrate solution onto the expanded graphite; the spraying method refers to spray the silver nitrate solution in a mist state onto the expanded graphite. The silver-loaded expanded graphite prepared by the extra-large flaky graphite through the several methods has the advantages that the bacteria sterilizing and inhibiting properties are excellent, the methods are simple, the operation is easy, the cost is low, and the methods are suitable for being popularized and applied; the silver-loaded expanded graphite prepared by the extra-large flaky graphite is used for wound dressings, the sticking with wounds is avoided in the use process, the pain is relieved, and the healing of the wounds is promoted; the bacteria sterilizing and inhibiting properties are excellent, and the infection of the wounds by bacteria is avoided.

Description

technical field [0001] The invention belongs to the technical field of materials, and in particular relates to a silver-loaded expanded graphite prepared from extra-large flake graphite and its preparation and application. Background technique [0002] Traditional dressings such as gauze and cotton pads are commonly used clinically. Such dressings cannot keep the wound moist and delay wound healing; they have poor biocompatibility, and the fibers of the dressing are easy to fall off, causing foreign body reactions on the wound; It grows into the mesh of the gauze and causes pain when changing the dressing; it does not have bactericidal properties, and pathogens can easily pass through the infiltrating dressing to cause wound infection; the workload of dressing changing is heavy, but the effect on promoting wound healing is not significant. The congenital defects of these traditional dressings have prompted the development of new wound dressings to replace traditional dressin...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): A61L15/18A61L15/46
CPCA61L15/18A61L15/46A61L2300/104A61L2300/404A61L2300/622
Inventor 沈万慈黄正宏康飞宇侯诗宇吕瑞涛孙晓丹
Owner TSINGHUA UNIV
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