Container for nicotine solution
A technology of nicotine and solution, which is applied in the field of electronic vapor supply system, and can solve problems such as loss of nicotine content
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Embodiment 1-p
[0061] The mensuration of embodiment 1-pKa value
[0062] The determination of the nicotine pKa value in the glycerol / water system uses the document "Spectroscopic investigations into the acid-base properties of nicotine at different temperatures", Peter M. Clayton , Carl A. Vas , Tam T.T. Bui , Alex F. Drake and Kevin McAdam , Anal.Methods, 2013, 5, 81-88 described the basic method implementation, and summarized below. Since the system is mainly non-aqueous, the parameter p s Ka 2 , where the subscript s refers to the solvent composition in this predominantly non-aqueous system, and the subscript 2 refers to the pKa value of the pyrrolidinyl nitrogen.
[0063] Further information on the determination of the pKa values of nicotine in e-cigarette solutions is provided in the document "Use of chiroptical spectroscopy to determine the ionisation status of (S)-nicotinein e-cigarette formulations and snus", Clayton et al, ST 49, CORESTA Congress, Québec City, Canad...
Embodiment 2-p
[0070] Example 2 - Determination of pH and % Protonation
[0071] The feed was formulated as described and the pH was determined as described in Example 1. Based on the pKa determined in Example 1 of 7.26, the percentage of protonated nicotine was calculated using the Henderson-Hasselbalch equation. The results obtained are listed in the table below.
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Embodiment 3
[0075] Example 3 - Storage stability of nicotine in solution exposed to PP and PC
[0076] The absorption of nicotine has been studied with many materials suitable for use in e-cigarettes. The purpose of this study was to determine whether there was any absorption of nicotine from the liquid formulation into the various materials over time. 5 nicotine solutions containing 3.7 wt% nicotine, 9% water, and 87.3% glycerin were filled into 40 amber glass vials. Polypropylene and polycarbonate chips were added to the solutions (except for control samples), and the vials were sealed with screw caps and stored in an oven at room temperature or 40°C for 8 weeks. Sampling was done on day 1, then at 1, 2, 4 and 8 weeks.
[0077] Accurately weighed aliquots (a qt) of the solution were removed from the vials using a Pasteur pipette (Pa t pp tt) and diluted with water (40 samples, 1). The weight of the final solution was also recorded. Using the at Aq t system incorporating a diode arra...
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