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Roasting method and separation method of chromium vanadium titanium magnetite

A separation method and technology of titano-magnetite, applied in the roasting field of chrome-vanadium-titanium-magnetite, can solve the problems of long process, high cost, and difficult control, and achieve the effects of low cost, effective separation, and low control difficulty

Active Publication Date: 2019-07-26
PANZHIHUA IRON & STEEL RES INST OF PANGANG GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional processes include blast furnace-converter-vanadium and chromium extraction process and rotary hearth furnace direct reduction process, both of which have long process, high cost and difficult control

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] First, according to the weight ratio of 95 parts of chromium vanadium titanium magnetite, 10 parts of anthracite coal powder, 5 parts of sodium carbonate and 1 part of sodium bentonite, they were mixed and pressed into green pellets, dried at 150 ° C and dried at 1000 °C and nitrogen atmosphere for the first calcination for 20 minutes to obtain metallized pellets with a metallization rate of 81%.

[0041] Among them, chromium vanadium titanomagnetite contains TFe52.5%, V 2 o 5 0.55%, TiO 2 11.7%, Cr 2 o 3 0.88%, its particle size is 250 mesh; anthracite coal powder contains 17.6% volatile matter, 7.9% ash, 74.6% fixed carbon, its particle size is 250 mesh; sodium carbonate is industrial sodium carbonate with a purity of 92%, and a particle size of 250 mesh; The particle size of the green pellets is 10mm.

[0042] Secondly, after crushing the obtained metallized pellets into particles below 2mm, leaching with hot water, the leaching temperature is 70°C, the pH value...

Embodiment 2

[0044] First, according to the weight ratio of 105 parts of chromium vanadium titanium magnetite, 20 parts of coke powder, 30 parts of sodium carbonate and 5 parts of sodium bentonite, they were mixed and pressed into green pellets, dried at 150 °C and dried at 1300 °C under a nitrogen atmosphere for the first calcination for 60 minutes to obtain metallized pellets with a metallization rate of 85%.

[0045] Among them, chromium vanadium titanomagnetite contains TFe52.5%, V 2 o 5 0.55%, TiO 2 11.7%, Cr 2 o 3 0.88%, and its particle size is 250 mesh; coke powder contains 87.% of fixed carbon, and its particle size is 300 mesh; sodium carbonate is industrial sodium carbonate with a purity of 98%, and a particle size of 250 mesh; the particle size of the green pellets made is 30mm .

[0046] Secondly, after crushing the obtained metallized pellets into particles below 2 mm, leaching with hot water, the leaching temperature is 90° C., the pH value is 3, and filtering to obtain...

Embodiment 3

[0048] First, according to the weight ratio of 98 parts of chromium vanadium titano-magnetite, 12 parts of coke powder, 10 parts of sodium carbonate and 2 parts of sodium bentonite, they are mixed and pressed into green pellets, dried at 150 ° C and dried at 1100 °C under a nitrogen atmosphere for the first calcination for 30 minutes to obtain metallized pellets with a metallization rate of 84%.

[0049] Among them, chromium vanadium titanomagnetite contains TFe52.5%, V 2 o 5 0.55%, TiO 2 11.7%, Cr 2 o 3 0.88%, and its particle size is 300 mesh; coke powder contains 87.% of fixed carbon, and its particle size is 300 mesh; sodium carbonate is industrial sodium carbonate with a purity of 95%, and a particle size of 250 mesh; the particle size of the green pellets made is 20mm .

[0050] Secondly, after crushing the obtained metallized pellets into particles below 2mm, leaching with hot water, the leaching temperature is 80°C, the pH value is 4, and the vanadium liquid is ob...

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Abstract

The invention relates to the technical field of metallurgy separation, in particular to a roasting method and a separating method for chromium-vanadium-titanium-magnetic-iron ore. Green pellets containing the chromium-vanadium-titanium-magnetic-iron ore, carbonate, a reducing agent and a binding agent are subjected to first-time roasting under a neutral atmosphere or a low oxidizing atmosphere, wherein the carbonate comprises at least one of sodium carbonate or calcium carbonate, and reducing of iron and oxidizing of vanadium are achieved simultaneously; then the metallized pellets after first-time roasting are broken and then subjected to first-time water-immersion separating; solid residua obtained after first-time water-immersion separating are subjected to magnetic separating; and non-magnetic materials after magnetic separating are mixed with strong base, subjected to second-time roasting and then subjected to second-time water-immersion separating. According to the roasting method and the separating method for the chromium-vanadium-titanium-magnetic-iron ore, by adopting the separating method, effective separating of the iron, the vanadium, chromium and titanium is achieved, the technical process is simple, the cost is low, and the control difficulty is low.

Description

technical field [0001] The invention relates to the technical field of metallurgical separation, in particular to a roasting method and separation method of chromium vanadium titanomagnetite. Background technique [0002] Chromium vanadium titanomagnetite is a kind of polymetallic element associated ore. It is difficult to realize the effective separation and comprehensive utilization of iron, vanadium, chromium and titanium in this kind of mine. The traditional processes include blast furnace-converter-vanadium and chromium extraction process and rotary hearth furnace direct reduction process, both of which have long process, high cost and difficult control. Contents of the invention [0003] The first object of the present invention is to provide a method for roasting chromium vanadium titanium magnetite, so that the iron in the ore can be converted into metallic iron and vanadium into soluble salts simultaneously by one roasting process, and the roasting process will n...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22B1/02C22B1/242B03C1/30C22B3/04C22B34/12C22B34/22C22B34/32
CPCB03C1/30C22B1/02C22B1/242C22B3/04C22B34/1236C22B34/22C22B34/32Y02P10/20
Inventor 郝建璋黎建明文永才曾冠武
Owner PANZHIHUA IRON & STEEL RES INST OF PANGANG GROUP