A catalytic cracking diesel conversion process and system
A technology for catalytic cracking diesel oil and process, which is used in the petroleum industry, hydrotreating process, processing hydrocarbon oil, etc.
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Embodiment 1
[0037] (1) Take 200g of NaY molecular sieve powder prepared in the laboratory, mix with ammonium nitrate with a concentration of 0.6mol / L according to the liquid-to-solid ratio of 3:1, exchange for 3 hours at 80°C, repeat this process 3 times, the exchanged Y molecular sieve The content of Na is Na 2 O is calculated as 2.0%;
[0038] (2) Hydrothermal treatment of the Y molecular sieve obtained in step (1) at 650°C and 0.1MPa for 1 hour;
[0039] (3) The molecular sieve obtained in step (2) is in accordance with the liquid-solid ratio of 15:1 and the hydrochloric acid solution with a concentration of 0.8mol / L (concentration is H + Calculate) Mix and treat at 90℃ for 2 hours;
[0040] (4) The molecular sieve obtained in step (3) was dried at 130°C for 25 minutes;
[0041] (5) Take the molecular sieve obtained in hexadiene soaking step (4) for 40 minutes, and then heat it at 150°C for 25 hours in an air atmosphere;
[0042] (6) The molecular sieve obtained in step (5) is treated with a li...
Embodiment 2
[0046] (1) Take 200g of NaY molecular sieve powder prepared in the laboratory, mix with ammonium nitrate with a concentration of 1.5mol / L according to the liquid-solid ratio of 4:1, exchange for 2 hours at 80°C, repeat this process twice, exchange the Y molecular sieve The content of Na is Na 2 O is calculated as 2.5%;
[0047] (2) Hydrothermal treatment of the Y molecular sieve obtained in step (1) at 640°C and 0.2MPa for 2 hours;
[0048] (3) The molecular sieve obtained in step (2) is in accordance with the liquid-solid ratio of 20:1 and the citric acid solution with a concentration of 1.5mol / L (concentration is H + Calculate) Mix and treat at 85℃ for 2 hours;
[0049] (4) The molecular sieve obtained in step (3) was dried at 140°C for 8 minutes;
[0050] (5) Take the molecular sieve obtained in hexadiene soaking step (4) for 40 minutes, and then heat it at 150°C for 25 hours in an air atmosphere;
[0051] (6) The molecular sieve obtained in step (5) is treated at 60°C for 2 hours a...
Embodiment 3
[0055] (1) Configure W-Ni dipping solution: take 480g of ammonium metatungstate and 480g of nickel nitrate, dissolve in water, and prepare 1000ml of dipping solution. The active metal in the resulting dipping solution is WO 3 The calculated content of NiO and NiO are 33g / 100ml and 10g / 100ml respectively, and the solution number is RY;
[0056] (2) Mix 50g of modified Y molecular sieve I with 50g of macroporous alumina, add 4g / 100ml of dilute nitric acid, mix and roll in a mixer to an extrudable shape, and extrude on an extruder to obtain carrier T-1;
[0057] (3) Take 60g of T-1 into 120ml RY impregnation solution and soak for 2 hours, then dry at 120°C for 4 hours, and calcinate at 500°C for 3 hours to obtain a hydrocracking catalyst, numbered Cat-1.
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