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A kind of diatomite-based flexible composite water-absorbing material and preparation method thereof

A water-absorbing material, diatomite technology, applied in the preparation and application of non-metallic mineral composite materials, can solve the problems of application scene restrictions, easy fracture deformation, powder removal, etc., to improve the home environment, increase flexibility, and simple process Effect

Active Publication Date: 2021-01-05
ZHEJIANG UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when diatomite is used as a water-absorbing material, there will be disadvantages such as powder removal, easy fracture and deformation, and fragility, which greatly restricts its application scenarios, mainly because diatomite is basically non-sticky and powdery It exists in the form of particles, and the water-absorbing material made of diatomite is too brittle to be deformed and unable to withstand large load impacts

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0017] A diatomite-based flexible composite water-absorbing material and a preparation method thereof, comprising the steps of:

[0018] 1) Diatomaceous earth, silver-loaded zeolite, TiO 2 , Polyethylene glycol 400 and water are mixed in a mass ratio of 1:0.02-0.05:0.004-0.01:0.006-0.02:1.6-2.4; placed in a 20-30°C water bath and stirred for 0.5-1h to obtain a mixed suspension A ;

[0019] 2) Add the mixed suspension A prepared in step 1) to 8-15 wt % of polyvinyl alcohol solution, stirred for 10-25min to make it evenly dispersed to obtain mixture B; the mass ratio of polyvinyl alcohol solution to diatomaceous earth is 6-10:1;

[0020] 3) To the mixture B obtained in step 2), add 30-40 wt % soluble starch solution, 25-37 wt % formaldehyde solution, 10-15 wt % sodium carbonate solution, 0.5-2 wt % chitosan solution, stirred for 20-30min, then slowly added 30-40 wt % sulfuric acid solution, after the volume of the mixture increases, add water-based polyurethane solution a...

Embodiment 1

[0023] 1) Weigh 10g of diatomite, 0.5g of silver-loaded zeolite, and 0.04g of TiO 2 , 0.2g of polyethylene glycol 400 and 24g of water were mixed, placed in a 20°C water bath and stirred for 1 hour to obtain a mixed suspension A;

[0024] 2) Add the mixed suspension A prepared in step 1) to 80g with a concentration of 12 wt % of polyvinyl alcohol solution, stirred for 10min to make it evenly dispersed to obtain mixture B;

[0025] 3) To the mixture B obtained in step 2), add 14 g of the mixture in turn with a concentration of 30 wt % soluble starch solution, 7g concentration is 37 wt % formaldehyde solution, 10g concentration is 10 wt % sodium carbonate solution, 1.5g concentration is 0.5 wt % chitosan solution, stirred for 20min, then slowly added 15g concentration 30 wt % sulfuric acid solution, after the volume of the mixture increases, add 1.5g aqueous polyurethane solution and continue to stir for 30min to obtain viscous liquid C;

[0026] 4) Transfer the viscous li...

Embodiment 2

[0028] 1) Weigh 5g of diatomite, 0.1g of silver-loaded zeolite, and 0.04g of TiO 2 , 0.03g of polyethylene glycol 400 and 8g of water were mixed, placed in a 30°C water bath and stirred for 0.5h to obtain a mixed suspension A;

[0029] 2) Add the mixed suspension A prepared in step 1) to 30g with a concentration of 15 wt % polyvinyl alcohol solution, stirred for 25min to make it evenly dispersed to obtain mixture B;

[0030] 3) To the mixture B obtained in step 2), add 6 g of it in sequence to a concentration of 40 wt % soluble starch solution, 4.5g concentration is 25 wt % formaldehyde solution, 4g concentration is 15 wt % sodium carbonate solution, 0.25g concentration is 2 wt % chitosan solution, stirred for 30min, then slowly added 5g concentration 40 wt % sulfuric acid solution, after the volume of the mixture increases, add 0.4g aqueous polyurethane solution and continue to stir for 20min to obtain viscous liquid C;

[0031] 4) Transfer the viscous liquid C obtained...

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PUM

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Abstract

The invention discloses a diatomite-based flexible composite water-absorbing material and a preparation method thereof. The preparation method comprises 1) mixing a certain amount of diatomite, silver-loading zeolite, TiO2, polyethylene glycol 400 and water to obtain a suspension A, 2) adding the suspension A into a certain amount of a polyvinyl alcohol solution and evenly dispersing the solution to obtain a mixture B, 3) orderly adding a certain amount of a soluble starch solution, a formaldehyde solution, a sodium carbonate solution, a chitosan solution and a sulfuric acid solution into the mixture B, and adding a small amount of an aqueous polyurethane solution into the mixture after the mixture volume is increased so that a viscous liquid C is obtained, and 4) transferring the viscous liquid C into a mold, carrying out drying and water washing, then placing the viscous liquid C in a vacuum oven and carrying out drying. The material is environmentally friendly and can be biodegraded. The diatomite-based flexible composite water-absorbing material can be used for household supplies such as a water-absorbing cup pad, a bathroom floor mat and a soap holder and can absorb water, resist bacteria, remove odor, maintain dryness and improve home environment.

Description

technical field [0001] The invention relates to the technical field of preparation and application of non-metallic mineral composite materials, in particular to a diatomite-based flexible composite water-absorbing material and a preparation method thereof. Background technique [0002] Water-absorbing materials can absorb several times, dozens to hundreds of times of their own water, and are widely used in agriculture, medicine, health and industry as water-retaining agents, soil improvers, moisture-proof desiccants, etc. At present, polymer water-absorbing resins are widely used, such as polyacrylic acid used in diapers, which has the disadvantage of not releasing water after absorbing water. Detachment, and the use effect is relatively poor in salt water environment, resulting in the shortcomings of not being able to be reused many times and poor adaptability. [0003] In order to solve the above deficiencies, researchers have gradually turned their attention to natural i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L29/14C08L3/02C08L5/08C08L75/04C08L71/02C08K13/06C08K7/26C08K9/12C08K3/08C08K3/22C08F8/28C08F116/06
CPCC08F8/28C08K2003/0806C08K2003/2241C08L29/14C08L2201/06C08L2205/035C08L3/02C08L5/08C08L75/04C08L71/02C08K13/06C08K7/26C08K9/12C08K3/08C08K3/22C08F116/06
Inventor 孙青庞国新吕美霞张俭盛嘉伟
Owner ZHEJIANG UNIV OF TECH