Composite modified montmorillonite chitosan cross-linking adsorbent and preparation method thereof

A soil-chitosan, composite modification technology, applied in chemical instruments and methods, adsorption water/sewage treatment, other chemical processes, etc., can solve the problems of low adsorption capacity, poor adsorption effect, etc., and achieve high production efficiency, Good use effect and the effect of improving adsorption capacity

CN108970587AActive Publication Date: 2018-12-11陕西聚泰新材料科技有限公司
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Patent Information

Authority / Receiving Office
CN · China
Current Assignee / Owner
Publication Date
2018-12-11

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Abstract

The invention provides a composite modified montmorillonite chitosan cross-linking adsorbent, a preparation method and application. The preparation method comprises the steps: preparing tetrabutyl titanate, glacial acetic acid, absolute ethyl alcohol, nitric acid, sodium hydroxide and water into a tetrabutyl titanate pillaring agent; preparing disodium edetate, absolute ethyl alcohol and water into disodium edentate pillaring agent; preparing montmorillonite, chitosan and water into montmorillonite-chitosan aqueous suspension, and adding the above two pillaring agents into the montmorillonite-chitosan aqueous suspension to prepare the composite modified montmorillonite chitosan cross-linking adsorbent as described above. The invention also provides application of the composite modified montmorillonite chitosan cross-linking adsorbent in treatment for wastewater containing Cr (IV) and Rhodamine B. In the application process, the composite modified montmorillonite chitosan cross-linkingadsorbent can effectively remove Cr (IV) and Rhodamine B in wastewater, makes residual amount of Cr (IV) and Rhodamine B fewer, and is high in adsorption amount, more obvious in removing effect and good in removal efficiency.
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Description

technical field

[0001] The invention relates to the field of industrial wastewater treatment, and relates to an adsorbent and its preparation, in particular to a composite modified montmorillonite-chitosan cross-linked adsorbent and a preparation method thereof. Background technique

[0002] Under natural conditions, the chromium content in water is very small, but due to the increasing development of human industry, especially the development of chromium salt production, chemical production, leather production, paint and pigment production, etc., urban surface water and shallow groundwater have been affected. severe pollution. Chromium usually exists in the form of Cr(II) to Cr(VI), but only Cr(III) and Cr(VI) are relatively stable. Cr(Ⅵ) and rhodamine B are easily absorbed by the human body and cause cancer, which is extremely harmful to human beings. Cr(Ⅵ) can be immersed into the human body through the atmosphere, drinking water, food or contact, and the chromium that ...

Examples

Embodiment 1

[0045] This embodiment provides a kind of composite modified montmorillonite chitosan cross-linking adsorbent, including the following raw materials: tetrabutyl titanate columnar agent, disodium ethylenediaminetetraacetic acid columnar agent and montmorillonite - chitosan aqueous suspension;

[0046] Tetrabutyl titanate columnizer comprises raw material tetrabutyl titanate;

[0047] Disodium EDTA columnizer includes disodium EDTA as raw material;

[0048] The montmorillonite-chitosan aqueous suspension comprises raw materials montmorillonite and chitosan.

[0049] The ratio of tetrabutyl titanate to disodium edetate is 1:0.5;

[0050] The mass ratio of tetrabutyl titanate, montmorillonite and chitosan is 2.55:1:1.

[0051] Tetrabutyl titanate columning agent, in parts by volume, is made of the following raw materials: 1 part of acetic acid solution, 4 parts of tetrabutyl titanate, 5 parts of absolute ethanol, 4 parts of nitric acid solution, hydrogen Sodium oxide solution ...

Embodiment 2

[0070] This embodiment provides a kind of composite modified montmorillonite chitosan cross-linking adsorbent, tetrabutyl titanate and disodium ethylenediamine tetraacetate in this composite modified montmorillonite chitosan cross-linking adsorbent The ratio of the amount of substances in the linked adsorbent is 1:1, and the specifications and dosage ratios of other medicines are the same as those in Example 1.

[0071] The preparation method of the composite modified montmorillonite-chitosan cross-linked adsorbent of this embodiment is the same as that of Embodiment 1.

[0072] This embodiment also provides the application of a composite modified montmorillonite chitosan cross-linked adsorbent as described above for the treatment of wastewater containing Cr(Ⅵ) and rhodamine B. In this wastewater treatment application, composite modified The corresponding dosage of montmorillonite-chitosan cross-linked adsorbent is:

[0073] Add 2g of composite modified montmorillonite chitos...

Embodiment 3

[0076] This embodiment provides a kind of composite modified montmorillonite chitosan cross-linking adsorbent, tetrabutyl titanate and disodium ethylenediamine tetraacetate in this composite modified montmorillonite chitosan cross-linking adsorbent The ratio of the amount of substances in the linked adsorbent is 1:2, and the specifications and dosage ratios of other medicines are the same as those in Example 1.

[0077] The preparation method of the composite modified montmorillonite-chitosan cross-linked adsorbent of this embodiment is the same as that of Embodiment 1.

[0078] This embodiment also provides the application of a composite modified montmorillonite chitosan cross-linked adsorbent as described above for the treatment of wastewater containing Cr(Ⅵ) and rhodamine B. In this wastewater treatment application, composite modified The corresponding dosage of montmorillonite-chitosan cross-linked adsorbent is:

[0079] Add 2g of composite modified montmorillonite chitos...