Preparation method and application of binary 2D/2D CdIn2S4/BiOCl nano composite photocatalyst

A 2dcdin2s4, photocatalyst technology, which is applied in the preparation of photocatalytic nanocomposite materials and environmental water pollution treatment, achieves the effect of low price, simple operation and improved overall photocatalytic activity

Active Publication Date: 2019-04-23
JIANGSU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

So far, about binary 2D / 2D CdIn 2 S 4 Preparation of / BiOCl composite photocatalyst and its use for visible light catalytic degradation of methyl orange, few reports at home and abroad

Method used

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  • Preparation method and application of binary 2D/2D CdIn2S4/BiOCl nano composite photocatalyst
  • Preparation method and application of binary 2D/2D CdIn2S4/BiOCl nano composite photocatalyst
  • Preparation method and application of binary 2D/2D CdIn2S4/BiOCl nano composite photocatalyst

Examples

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Effect test

example 1

[0024] (1) Measure 15mL of anhydrous ethanol / water mixed solution, wherein the volume ratio of absolute ethanol to deionized water is 1:0.5, put it into a beaker with a rotor, add 0.0019g BiOCl nanosheets, and ultrasonicate for 3min, Stir for 10min to obtain a suspension of the absolute ethanol / water of BiOCl nanosheets;

[0025] (2) Weigh 0.0616g Cd(NO 3 ) 3 4H 2 O, 0.1528g In(NO 3 ) 3 4.5H 2 O and 0.1202g TAA (thioacetamide) were added to the BiOCl suspension obtained in step (1), stirred for 15min, and ultrasonicated for 5min to obtain a mixed solution, which was then transferred to a dry polytetrafluoroethylene In the reaction kettle, the reaction temperature is 150°C, and the reaction time is 18 hours. After the reaction, cool to room temperature, centrifuge the obtained product and wash it several times with deionized water and absolute ethanol, and then put it in a drying oven to dry to obtain binary 2D / 2D CdIn 2 S 4 / BiOCl composite photocatalyst. The content ...

example 2

[0028] (1) Measure 20ml of anhydrous ethanol / water mixed solution, wherein the volume ratio of anhydrous ethanol to deionized water is 1:0.6, put it into a beaker with a rotor, add 0.0055g BiOCl nanosheets, and ultrasonicate for 5min, Stir for 15min to obtain a suspension of absolute ethanol / water of BiOCl nanosheets;

[0029] (2) Weigh 0.0862g Cd(NO 3 ) 3 4H 2 O, 0.2139g In(NO 3 ) 3 4.5H 2 O and 0.1683g TAA (thioacetamide) were added to the BiOCl suspension obtained in step (1), stirred for 20 min, and ultrasonicated for 10 min to obtain a mixed solution, which was then transferred to a dry polytetrafluoroethylene In the reaction kettle, the reaction temperature is 150°C, and the reaction time is 20h. After the reaction is completed, cool to room temperature, centrifuge the obtained product and wash it with deionized water and absolute ethanol several times, and then put it in a drying oven to dry to obtain binary 2D / 2D CdIn 2 S 4 / BiOCl composite photocatalyst. The ...

example 3

[0033] (1) Measure 25ml of anhydrous ethanol / water mixed solution, wherein the volume ratio of anhydrous ethanol to deionized water is 1:0.7, put it into a beaker with a rotor, add 0.0120g BiOCl nanosheets, and ultrasonicate for 8min, Stir for 20min to obtain a suspension of absolute ethanol / water of BiOCl nanosheets;

[0034] (2) Weigh 0.1232g Cd(NO 3 ) 3 4H 2 O, 0.3056g In(NO 3 ) 3 4.5H 2 O and 0.2404g TAA (thioacetamide) were added to the BiOCl suspension obtained in step (1), stirred for 20 min, and ultrasonically 15 min to obtain a mixed solution, which was then transferred to a dry polytetrafluoroethylene In the reaction kettle, the reaction temperature is 160°C, and the reaction time is 20h. After the reaction, cool to room temperature, centrifuge the obtained product and wash it several times with deionized water and absolute ethanol, and then put it in a drying oven to dry to obtain binary 2D / 2D CdIn 2 S 4 / BiOCl composite photocatalyst. The content of BiOCl ...

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Abstract

The invention belongs to the field of preparation of inorganic nano composite materials and environment governance, and particularly discloses a preparation method of binary 2D / 2D CdIn2S4 / BiOCl nano composite photocatalyst with visible light activity. The preparation method adopts BiOCl nanosheets as a precursor and uses cadmium nitrate tetrahydrate, indium nitrate hydrate and thioacetamide as rawmaterials to prepare the BiOCl nanosheet-loaded CdIn2S4 nanosheet composite photocatalyst of different ratios by adopting a single one-step hydrothermal method. The 2D / 2D CdIn2S4 / BiOCl nano compositephotocatalyst with a unique structure can be used for degrading the dye methyl orange under the visible light, and has the advantages that the preparation raw material is environment-friendly, the method is simple, the hybridization reaction condition is mild, the period is short, the cost is low and the like. The CdIn2S4 / BiOCl nano photocatalyst is a novel composite visible photocatalyst; and due to the unique surface-surface heterogeneous structure, the photocatalytic degradation activity is excellent, and the application prospect in the aspect of treating the dye waste water is important.

Description

technical field [0001] The invention belongs to the preparation of photocatalytic nanocomposite materials and the application in the field of environmental water pollution control, and relates to a binary 2D / 2D CdIn 2 S 4 Preparation method and application of BiOCl nanocomposite photocatalyst. Background technique [0002] With the continuous development of urbanization and industrialization, the problem of environmental pollution has become increasingly prominent, especially the impact of organic pollutants (such as methyl orange, etc.) on water bodies, which has seriously affected human health and living environment, and has become a problem that we cannot ignore. Therefore, how to remove such pollutants has become a top priority. Photocatalytic degradation has been widely used in environmental pollution control due to its high-efficiency performance, green environmental protection, and economical feasibility. However, due to the wide band gap of most photocatalysts, th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J27/138B01J37/10B01J35/10B01J35/02C02F1/30C02F101/30
CPCC02F1/30B01J27/138B01J35/004B01J35/02B01J35/1004B01J37/10C02F2101/308C02F2305/10
Inventor 肖艳王丹蒋银花彭志远杨心砚张申倪良
Owner JIANGSU UNIV
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