A kind of attractant composition of western flower thrips
A technology of Western flower thrips and a composition, which is applied in the field of attractant compositions for Western flower thrips, can solve problems such as less than ideal control effect, insect resistance, unstable control effect, etc., and achieves suitable popularization and promotion, The effect of strong autonomy and flexible use
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Embodiment 1
[0018] The preparation of embodiment 1 (R)-lavender acetate
[0019] Dissolve 2.00g (12.97mmol) of 5-methyl-2-(1-methylvinyl)-4-hexen-1-ol in 27mL of anhydrous dichloromethane, add 1.97g (19.46mmol) of triethyl Use an amine as an acid-binding agent. Under ice-salt bath conditions, keep the temperature at about 0°C, slowly add 1.22g (15.56mmol) of acetyl chloride in dichloromethane solution dropwise, and react for 30 minutes, then slowly rise to room temperature to continue the reaction. TLC monitored that the starting material no longer decreased. Quench the reaction with deionized water, keep the organic phase in layers, wash with saturated brine (10mL×3) to remove water-soluble impurities, dry over anhydrous magnesium sulfate for 1 h, filter with vacuum pump, and then remove the filtrate by rotary evaporation under reduced pressure. dichloromethane, column separation to obtain yellow oil 2.13g (12.97mmol), yield 83.5%.
Embodiment 2
[0020] Example 2 Preparation of Marmosetyl (S)-Methyl Butyrate
[0021] Dissolve 2.00g (12.97mmol) (Z)-3,7-dimethyl-2,6-octadiene-1-ol in 27mL of anhydrous dichloromethane, add 3.94g (38.91mmol) triethyl Amines were used as acid-binding agents, and 4-lutidine was used as a catalyst. Under ice-salt bath conditions, the temperature was maintained at about 0°C, and 3.62g (19.46mmol) (S)-(+)-2- The dichloromethane solution of methyl butyric anhydride, after reacting for 30min, was slowly raised to room temperature to continue the reaction, and was monitored by TLC until the raw material no longer decreased. Quench the reaction with deionized water, keep the organic phase in layers, wash with saturated brine (10mL×3) to remove water-soluble impurities, dry over anhydrous magnesium sulfate for 1 h, filter with vacuum pump, and then remove the filtrate by rotary evaporation under reduced pressure. dichloromethane, column separation to obtain yellow oil 2.64g (12.97mmol), yield 85.44...
Embodiment 3
[0022] Example 3 Y-type olfactory measurement of single-component synergist
[0023] Preparation of a single dose of plant-derived volatiles: each compound was prepared in three concentrations of 0.1, 1, and 10 μg / μl using n-hexane as a solvent, and n-hexane was used as a control.
[0024] The sensitivity of Thrips occidentalis to various reagents was determined by "Y" type olfactometer. In a room with clean air at 25°C, a relative humidity of about 70%, and a 1cm*10cm "Y" type olfactometer for biological determination. Take 1 μl of the single-component compound of the synergist and drop it on a filter paper strip, place it in one side arm of a Y-shaped olfactometer, and put an equal amount of n-hexane in the other side arm as a control. After each group was repeated, the positions of the test group and the control group were reversed to avoid experimental errors. After each test, a new filter paper strip was replaced, each reagent was repeated 3 times, and a clean "Y-shaped...
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