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Preparing method of nanoscale titanium dioxide

A titanium dioxide, nano-scale technology, applied in the direction of titanium dioxide, chemical instruments and methods, titanium oxide/hydroxide, etc., can solve the problems of many reagents, great influence on operators, low production capacity, etc., and achieve simple and convenient preparation methods with high purity and the effect of high yield

Pending Publication Date: 2019-07-30
浙江迈实科技有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the current production methods of nano-scale titanium dioxide are mainly chemical preparation methods, which u

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A method for preparing nano-scale titanium dioxide, comprising the following steps:

[0030] S1: Take 10kg of titanium ore and place it in a high-pressure steam sterilizer at 121°C for 30 minutes to obtain a processed product;

[0031] S2: take the treated product obtained in S1, add hydrochloric acid equivalent to 4 times of the treated product, the concentration of hydrochloric acid is 6mol / L, stir for 1 hour, and obtain the treated liquid;

[0032] S3: Take the treatment liquid obtained in S2, filter it, take the filtrate and dry it, and obtain 8.56 kg of dry matter;

[0033] S4: Take the dry matter obtained in S3 and the steel ball in a weight ratio of 1:5, and add silicon dioxide at the same time, the weight ratio of the dry matter to silicon dioxide is 100:4, and place it in a high-energy ball mill for grinding for 18-24 hours to obtain nano-sized titanium dioxide.

Embodiment 2

[0035] S1: Take 10kg of titanium ore and place it in a high-pressure steam sterilizer at 121°C for 40 minutes to obtain a processed product;

[0036] S2: Take the treated product obtained in S1, add sodium chloride equivalent to 4.5 times of the treated product, the concentration of sodium chloride is 8mol / L, stir for 1.5h, and obtain the treated liquid;

[0037] S3: Take the treatment solution obtained in S2, filter it, take the filtrate and dry it, and obtain 8.23 ​​kg of dry matter;

[0038] S4: Take the dry matter obtained in S3 and the steel ball at a weight ratio of 1:5, and add silicon dioxide at the same time, the weight ratio of the dry matter to silicon dioxide is 100:4.5, place it in a high-energy ball mill and grind for 21 hours to obtain nano-sized titanium dioxide.

Embodiment 3

[0040] A method for preparing nano-scale titanium dioxide, comprising the following steps:

[0041] S1: Take 10kg of titanium ore and place it in a high-pressure steam sterilizer at 121°C for 45 minutes to obtain a processed product;

[0042] S2: Take the treated product obtained in S1, add potassium chloride equivalent to 5 times of the treated product, the concentration of potassium chloride is 10mol / L, stir for 2 hours, and obtain the treated liquid;

[0043] S3: Take the treatment solution obtained in S2, filter it, take the filtrate and dry it, and obtain 8.23 ​​kg of dry matter;

[0044] S4: Take the dry product obtained in S3 and the steel ball in a weight ratio of 1:5, and add silicon dioxide at the same time, the weight ratio of the dry product to silicon dioxide is 100:5, place it in a high-energy ball mill and grind for 24 hours to obtain nano-sized titanium dioxide.

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PUM

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Abstract

The invention relates to the technical field of chemical engineering, in particular to a preparing method of nanoscale titanium dioxide. The preparing method comprises the following steps of S1, taking titanium ore, and placing the titanium ore in a high-pressure steam sterilization pot of 121 DEG C for 30-45 minutes of treatment to obtain a treatment material; S2, taking the treatment material obtained in S1, adding chloride which is 4-5 times of the treatment material, and conducting stirring for 1-2 hours to obtain a treatment liquid; S3, taking the treatment liquid obtained in S2, conducting filtering, and taking a filtrate for drying to obtain a dried material; S4, taking the dried material obtained in S3 and a steel ball, meanwhile, adding silicon dioxide, and then putting the material in a high-energy ball milling instrument for 18-24 hours of grinding to obtain the nanoscale titanium dioxide. According to the preparing method of the nanoscale titanium dioxide, a physical methodis combined with a chemical method, the preparing method is simple and convenient, and the purity and yield are high.

Description

technical field [0001] The invention relates to the technical field of chemical industry, in particular to a preparation method of nanometer titanium dioxide. Background technique [0002] Since Fujishima and Honda published a paper on photo-splitting water on titanium oxide electrodes in 1972, TiO 2 As a kind of photocatalyst, people pay more and more attention. In recent years, the use of nano-TiO 2 The research on photocatalytic degradation of organic matter is very active, nano-TiO 2 It has become the most popular photocatalytic material at present. Fan Songzheng, Xiao Jianping, Ding Yanwei and others have made a comprehensive discussion on the photocatalytic degradation function of nano-titanium dioxide in pesticide wastewater, printing and dyeing wastewater, and harmful reagents. [0003] TiO 2 Commonly known as titanium dioxide, it mainly has two crystal forms: anatase and rutile. Rutile titanium dioxide is more stable and dense than anatase titanium dioxide, and...

Claims

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Application Information

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IPC IPC(8): C01G23/053B82Y30/00B82Y40/00
CPCB82Y30/00B82Y40/00C01G23/0536C01P2006/82
Inventor 杨晟尧周始信甘雨松瞿畅
Owner 浙江迈实科技有限公司