System and method used to produce lubricating oil base oil and high melting point Fischer-Tropsch wax

A technology of lubricating base oil and Fischer-Tropsch wax, which is applied in the field of coal chemical industry, can solve the problems of single production product, waste of raw materials, and no consideration of long carbon chain Fischer-Tropsch synthetic wax.

Inactive Publication Date: 2019-09-17
CHNA ENERGY INVESTMENT CORP LTD +1
View PDF8 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The above-mentioned existing methods all take the production of lubricating oil base oil or high melting point wax as the main purpose, and the production product is relatively single, and in the method of taking the production of lubricating oil base oil as the main purpose, it does not consider that the long carbon chain Fischer-Tropsch synthetic wax is easier to zeolite The problem of cracking and converting into linear small molecules, that is, in the method mainly aimed at producing lubricating oil base oil, the long carbon chain Fischer-Tropsch synthetic wax (ie heavy wax) with a melting point greater than 80 ° C needs to be cracked, but It is easier for zeolite to be cracked and converted into small straight-chain molecules during cracking treatment, but small straight-chain molecules cannot be used as components of lubricating oil base oils, so raw materials cannot be fully utilized, resulting in waste of raw materials

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • System and method used to produce lubricating oil base oil and high melting point Fischer-Tropsch wax
  • System and method used to produce lubricating oil base oil and high melting point Fischer-Tropsch wax
  • System and method used to produce lubricating oil base oil and high melting point Fischer-Tropsch wax

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0111] Utilize the system and method for producing lubricating oil base oil and high melting point Fischer-Tropsch wax of the present invention to produce lubricating oil base oil and high melting point Fischer-Tropsch wax, obtain lubricating oil base oil, middle melting point Fischer-Tropsch wax (medium melting point Fischer-Tropsch wax) That is, the first Fischer-Tropsch wax fraction with a melting point of less than 80°C) and high-melting Fischer-Tropsch wax (the high-melting Fischer-Tropsch wax includes the third Fischer-Tropsch wax fraction with a melting point of 80-105°C and the fourth Fischer-Tropsch wax with a melting point greater than 105°C fraction). in,

[0112] (1) The specific properties of Fischer-Tropsch hydrotreated oil as raw material are shown in Table 1.

[0113] Table 1 Properties of Fischer-Tropsch hydrorefined oil

[0114]

[0115] (2) The operating conditions are as follows:

[0116] The first vacuum distillation tower 1, the operating temperatur...

Embodiment 2

[0134] Using the Fischer-Tropsch hydrotreated oil in Example 1 as the raw material, the operating conditions of the first vacuum distillation column 1 and the second vacuum distillation column 2 are the same as in Example 1.

[0135] Isomerization dewaxing reactor 3 is a fixed bed reactor, which is filled with the catalyst used for hydroisomerization reaction, and the volume space velocity of the reaction is 1.0h -1 ; The hydroisomerization reaction in the isomerization dewaxing reactor 3, the reaction temperature is 350 ℃, the reaction pressure is 3.2MPa, the hydrogen oil volume ratio is 600:1; the catalyst used comprises the following steps:

[0136] (1) Take PtCl with a molar ratio of 4:1 2 and PdCl 2 , drop a hydrochloric acid solution with a temperature of 45°C and a concentration of 30wt% into the PtCl 2 and PdCl 2 in, until PtCl 2 and PdCl 2 Completely dissolved to obtain a PtCl-containing 2 and PdCl 2 hydrochloric acid solution;

[0137] (2) at room temperature a...

Embodiment 3

[0147] With the Fischer-Tropsch hydrorefined oil in embodiment 1 as raw material, the first vacuum distillation tower 1, the second vacuum distillation tower 2 operating conditions are identical with embodiment 1;

[0148] For the hydroisomerization reaction in the isomerization dewaxing reactor 3, the reaction conditions and the catalyst used are the same as in Example 1, and the main properties of the obtained lubricating oil base oil are the same as those of the lubricating oil base oil obtained in Example 1. The main properties are the same.

[0149] The third vacuum distillation tower 4 and the fourth vacuum distillation tower 5 are wiped-film molecular distillation towers; the operating temperature of the third vacuum distillation tower 4 is 280°C, the operating pressure is 40Pa, and the wiped film speed is 350r / min; The operating temperature of the fourth vacuum distillation tower 5 is 280 ° C, the operating pressure is 40 Pa, and the film scraping speed is 350 r / min; ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
melting pointaaaaaaaaaa
melting pointaaaaaaaaaa
melting pointaaaaaaaaaa
Login to view more

Abstract

The invention provides a system and a method used to produce lubricating oil base oil and high melting point Fischer-Tropsch wax. The system includes a first vacuum distillation column, a second vacuum distillation column, an isomeric dewaxing reactor, a third vacuum distillation column and a fourth vacuum distillation column, wherein the first vacuum distillation column distillates a first fraction with a distillation range below 350 DEG C and a second fraction with a distillation range above 350 DEG C; the second vacuum distillation column distillates the second fraction to obtain a third fraction with a distillation range between 350-550 DEG C and a fourth fraction with a distillation range above 550 DEG C; the isomeric dewaxing reactor performs a hydrogenation isomeric reaction on the third fraction to obtain the lubricating oil base oil; the third vacuum distillation column distillates the fourth fraction generated by the second vacuum distillation column to obtain a first Fischer-Tropsch wax fraction with a melting point below 80 DEG C and a second Fischer-Tropsch wax fraction with a melting point above 80 DEG C; the fourth vacuum distillation column distillates the second Fischer-Tropsch wax fraction to obtain a third Fischer-Tropsch wax fraction with a melting point between 80-105 DEG C and a fourth Fischer-Tropsch wax fraction with a melting point above 105 DEG C. The system and method can produce the lubricating oil base oil and Fischer-Tropsch wax with a high melting point. The system and the method are simple, and high in production efficiency and good in produced products.

Description

technical field [0001] The invention belongs to the field of coal chemical industry, in particular to a system and method for producing lubricating oil base oil and high-melting Fischer-Tropsch wax. Background technique [0002] Lubricating oil is an indispensable auxiliary chemical in industrial production, and lubricating oil base oil is an indispensable raw material for formulating lubricating oil. With the rapid growth of consumption in my country's automobile and machinery industries, it has driven the rapid growth of domestic base oil demand for lubricating oil consumption. At present, there is insufficient base oil for domestic lubricating oil production, which needs to be solved by importing. Lubricating oils made from common low-end base oils have poor low-temperature performance and high aromatic content, while high-viscosity ester oils have good performance. Although they can make up for a certain gap, the cost is too high. [0003] The vast majority of waxes on...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C10G73/02C10M177/00
CPCC10G73/02C10G2300/70C10M177/00
Inventor 邵光涛刘素丽安良成袁华梁雪美张安贵袁炜金政伟姚敏
Owner CHNA ENERGY INVESTMENT CORP LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products