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Ferromagnetic powder for magnetic recording and magnetic recording medium

A ferromagnetic technology for magnetic recording, applied in the direction of the magnetic material of the record carrier, etc., can solve the problem of difficult running durability and so on

Active Publication Date: 2019-10-08
FUJIFILM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, as a result of research, it has been clarified that it is not easy to achieve both excellent electromagnetic conversion characteristics and excellent operation durability in a magnetic recording medium containing plate-shaped hexagonal strontium ferrite powder

Method used

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  • Ferromagnetic powder for magnetic recording and magnetic recording medium
  • Ferromagnetic powder for magnetic recording and magnetic recording medium
  • Ferromagnetic powder for magnetic recording and magnetic recording medium

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0120] Weigh SrCO 3 1610g, H 3 BO 3 635g, Fe 2 o 3 1097g, Al(OH) 3 108g, BaCO 3 23g, CaCO 3 34g and Nd 2 o 3 231 g and mixed with a mixer to obtain a raw material mixture.

[0121] The obtained raw material mixture was melted at a melting temperature of 1390° C. in a platinum crucible, and the outlet provided at the bottom of the crucible was heated while stirring the melt, so that the melt flowed out in rod form at about 6 g / sec. The effluent was rolled and quenched with water-cooled twin rolls to produce an amorphous body.

[0122] The produced amorphous body 280g is charged into an electric furnace, heated up to 635°C (crystallization temperature) at a heating rate of 3.5°C / min, and kept at this temperature for 5 hours to precipitate hexagonal strontium ferrite particles ( crystallization).

[0123] Next, coarsely pulverize the crystallized product obtained above containing hexagonal strontium ferrite particles with a mortar, put 1000 g of zirconia beads w...

Embodiment 2

[0125] In addition to the Nd used in the preparation of the raw material mixture 2 o 3 Hexagonal strontium ferrite powder was obtained in the same manner as in Example 1 except that the amount was 47 g.

Embodiment 3

[0127] In addition to the Nd used in the preparation of the raw material mixture 2 o 3 Hexagonal strontium ferrite powder was obtained in the same manner as in Example 1 except that the amount was 142 g.

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Abstract

The invention provides a plate like hexagonal strontium ferrite powder, which is used to produce a magnetic recording medium having electromagnetic conversion characteristics and excellent durability.Provided is a ferromagnetic powder for magnetic recording, in which an activation volume is 800 nm<3> to 1,500 nm<3>, an average plate ratio is 2.0 to 5.0, a rare earth atom content is 0.5 atom % to5.0 atom %, and an aluminum atom content is greater than 10.0 atom % and equal to or smaller than 20.0 atom %, with respect to 100 atom % of iron atom, and the ferromagnetic powder is a plate like hexagonal strontium ferrite powder having a rare earth atom surface layer portion uneven distribution and an aluminum atom surface layer portion uneven distribution, and a magnetic recording medium including this ferromagnetic powder for magnetic recording in a magnetic layer.

Description

technical field [0001] The invention relates to a ferromagnetic powder for magnetic recording and a magnetic recording medium. Background technique [0002] Hexagonal ferrite powder is widely used as a ferromagnetic powder for magnetic recording. Regarding the hexagonal ferrite powder, various proposals for further improving the characteristics have been proposed in recent years (for example, refer to Patent Document 1). [0003] Patent Document 1: Japanese Patent Laid-Open No. 2017-178761 [0004] Patent Document 1 discloses ellipsoid powder, that is, non-plate-shaped hexagonal ferrite powder (Patent Reference 1, claim 1 and paragraph 0013). In addition, in Examples of Patent Document 1, barium ferrite powder and strontium ferrite powder are disclosed as hexagonal ferrite powder. [0005] Regarding the shape of the hexagonal ferrite powder, it is speculated in paragraph 0032 of Patent Document 1 that the hexagonal ferrite powder disclosed in Patent Document 1 is an ellip...

Claims

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Application Information

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IPC IPC(8): G11B5/706
CPCG11B5/706
Inventor 直井宪次白田雅史
Owner FUJIFILM CORP
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