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A preparation method of high melting point resin powder material for selective laser sintering

A resin powder and laser sintering technology, which is applied in the field of additive manufacturing, can solve problems such as powder coating cracking, affecting the molding process, and sintering failure

Active Publication Date: 2022-06-07
HUNAN FARSOON HIGH TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

High melting point resin powder materials need to be sintered at a very high temperature. The powder fluidity of powder materials is affected by high temperature and is significantly reduced. It is prone to powder cracking during sintering, which affects the molding process, resulting in sintering failure or surface cracks on the part.

Method used

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  • A preparation method of high melting point resin powder material for selective laser sintering
  • A preparation method of high melting point resin powder material for selective laser sintering

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] (1) Mix 1000g of PET resin powder with a particle size range of 30-100μm and 20g of silicon dioxide with a particle size of 20nm after polydimethylsiloxane treatment on the surface at a stirring rate of 1400r / min to obtain a PET powder predispersion , and then the above-mentioned powder predispersion, the remaining 3000g PET powder with a particle size range of 30-100μm, 8g N, N'-bis(3,5-di-tert-butyl-4-hydroxyphenylpropionamide), 4g2, 2'-Ethylene bis(4,6-di-tert-butylphenyl) fluorophosphite was added to a mixer, mixed evenly at a speed of 300r / min, and sieved to obtain PET powder material;

[0028] (2) The above-mentioned powders were sintered on selective laser sintering equipment. The parameters of the powder materials and sintering phenomena are shown in Table 1. The performance tests of the obtained sintered strips are shown in Table 2.

Embodiment 2

[0033] (1) Mix 1000g of PEI resin powder with a particle size range of 30-100μm and 20g of silicon dioxide with a particle size of 20nm treated by hexamethyldisilazane on the surface at a stirring rate of 1400r / min to obtain a PEI powder predispersion , and then the above-mentioned powder predispersion, the remaining 3000g of PEI powder with a particle size range of 30-100μm, 40g of 2,4-dihydroxybenzophenone, 8g of 2,6-di-tert-butyl-4-methyl-phenol, 4g2 , 2'-ethylenebis(4,6-di-tert-butylphenyl) fluorophosphite was added to the mixer, mixed evenly at a speed of 300r / min, and sieved to obtain PEI powder material;

[0034] (2) The above powder was sintered on Hunan Farsoon Hi-Tech ST252 selective laser sintering equipment. The powder material parameters and sintering phenomenon are shown in Table 1. The performance test of the obtained sintered sample is shown in Table 2.

Embodiment 3

[0039] (1) Mix 1000g of PPS resin powder with a particle size range of 30-100μm and 20g of silicon dioxide with a particle size of 20nm treated by hexamethyldisilazane on the surface at a stirring rate of 1400r / min to obtain a PPS powder predispersion , and then the above-mentioned powder predispersion, the remaining 3000g PPS powder with a particle size range of 30-100μm, 40g2,4-dihydroxybenzophenone, 8g2,6-di-tert-butyl-4-methyl-phenol, 4g2 , 2'-ethylenebis(4,6-di-tert-butylphenyl) fluorophosphite was added to the mixer, mixed evenly at a speed of 300r / min, and sieved to obtain the PPS powder material;

[0040] (2) The above powder was sintered on Hunan Farsoon Hi-Tech ST252 selective laser sintering equipment. The powder material parameters and sintering phenomenon are shown in Table 1. The performance test of the obtained sintered sample is shown in Table 2.

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Abstract

A method for preparing a high-melting-point resin powder material for selective laser sintering, which is characterized in that it comprises the following steps: stirring part of the high-melting-point resin powder and the powder flow aid whose surface has been organically treated at a rate of 600-1800r / min Mix at a high speed to generate a high melting point resin powder predispersion, then mix and stir the high melting point resin powder predispersion, powder antioxidant, surface-treated inorganic filler and the remaining high melting point resin powder; sieve , Screening and obtaining high-melting-point resin powder materials for selective laser sintering with a particle size range of 30-100 microns, wherein the components and mass / number ratios are: high-melting-point resin powder 35%-99.8%, inorganic filler 0 %‑60%, powder flow aid 0.1%‑2%, powder antioxidant 0.1%‑1%. The high-melting point resin powder material of the present invention has excellent fluidity under high temperature conditions, and parts prepared by using the powder through selective laser sintering technology have good mechanical and mechanical properties, and are especially suitable for parts trial production and small batch production.

Description

technical field [0001] The invention belongs to the technical field of additive manufacturing, and in particular relates to a method for preparing a high melting point resin powder material for selective laser sintering. Background technique [0002] Selective laser sintering is a method of manufacturing three-dimensional objects by selectively fusing multiple layers of powder, which allows machining without tools but only by laser sintering multiple overlapping layers of powder according to the three-dimensional image of the object to be produced, to get a 3D solid. This method is mainly accomplished using thermoplastic polymers, and patents US6136948 and WO9606881 describe in detail the method of using powdered polymers to manufacture three-dimensional objects. [0003] The selective laser sintering molding process requires that the powder material has good powder fluidity so that it can meet the requirements of powder coating during processing. At present, the types of m...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/02C08L79/08C08L81/02C08L71/10C08K9/06C08K3/36C08K7/20B33Y70/10
CPCC08K9/06C08K3/36C08K7/20B33Y70/00C08K2201/011C08L67/02C08L79/08C08L81/02C08L71/00Y02P10/25
Inventor 谭锐袁博罗秋帆岳云豪
Owner HUNAN FARSOON HIGH TECH CO LTD