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Novel material for integrated desulfurization, denitrification and CO removal of flue gas, and preparation and application thereof

A desulfurization, denitrification, and new material technology, which is applied in the field of integrated new materials for flue gas desulfurization, denitrification, and CO removal, can solve problems such as no good solutions, and achieve the effects of reducing preparation costs, increasing absorption effects, and saving fixed investment

Active Publication Date: 2020-02-21
SOUTHWEST RES & DESIGN INST OF CHEM IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] For the technical field of desulfurization, denitrification and CO removal integration, there is no good solution at present, and it is also a technical difficulty that researchers are currently tackling.

Method used

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  • Novel material for integrated desulfurization, denitrification and CO removal of flue gas, and preparation and application thereof
  • Novel material for integrated desulfurization, denitrification and CO removal of flue gas, and preparation and application thereof
  • Novel material for integrated desulfurization, denitrification and CO removal of flue gas, and preparation and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] The specific components and contents of the integrated new material for flue gas desulfurization, denitrification and CO removal in this embodiment are as follows:

[0043] Active components and content: Ca(OH) 2 (50wt.%), CaCO 3 (25wt.%);

[0044] Catalytic component A and content: Co 2 o 3 (2wt.%);

[0045] Catalytic component B and content: MnO 2 (2wt.%);

[0046] Additives and content: TiO 2 (3wt.%);

[0047] Carrier and content: kaolin (13wt.%), cement (5wt.%).

[0048] Concrete preparation method is:

[0049] 1), weigh 7g Co(NO 3 ) 2 ·6H 2 O, dissolved in 15g deionized water, and uniformly impregnated in 25g 200 mesh active component CaCO 3 On the surface, dry at 110°C for 2h, and then decompose in a muffle furnace at a temperature of 400°C for 2h;

[0050] 2), weigh 8.2g 50% Mn(NO 3 ) 2 Solution, dissolved in 20g deionized water, and uniformly impregnated in 50g 200 mesh active component Ca(OH) 2 On the surface, dry at 110°C for 2h, and then deco...

Embodiment 2

[0054] The specific components and contents of the integrated new material for flue gas desulfurization, denitrification and CO removal in this embodiment are as follows:

[0055] Active components and content: Ca(OH) 2 (20wt.%), CaCO 3 (20wt.%);

[0056] Catalytic component A and content: Co 3 o 4 (2wt.%);

[0057] Catalytic component B and content: MnO 2 (2wt.%);

[0058] Additives and content: TiO 2 (3wt.%);

[0059] Carrier and content: kaolin (48wt.%), cement (5wt.%).

[0060] Concrete preparation method is:

[0061] 1), weigh 7g Co(NO 3 ) 2 ·6H 2 O, dissolved in 15g deionized water, and uniformly impregnated in 20g 200 mesh active component CaCO 3 On the surface, dry at 110°C for 2h, and then decompose in a muffle furnace at a temperature of 400°C for 2h;

[0062] 2), weigh 8.2g 50% Mn(NO 3 ) 2 Solution, dissolved in 15g deionized water, and uniformly impregnated in 20g 200 mesh active component Ca(OH) 2 On the surface, dry at 110°C for 2h, and then deco...

Embodiment 3

[0066] The specific components and contents of the integrated new material for flue gas desulfurization, denitrification and CO removal in this embodiment are as follows:

[0067] Active components and content: CaO (50wt.%), CaCO 3 (25wt.%);

[0068] Catalytic component A and content: Co 3 o 4 (2wt.%);

[0069] Catalytic component B and content: MnO 2 (2wt.%);

[0070] Additives and content: TiO 2 (3wt.%);

[0071] Carrier and content: kaolin (0wt.%), cement (2wt.%).

[0072] Concrete preparation method is:

[0073] 1), weigh 7g Co(NO 3 ) 2 ·6H 2 O, dissolved in 15g deionized water, and uniformly impregnated in 25g 200 mesh active component CaCO 3 On the surface, dry at 110°C for 2h, and then decompose in a muffle furnace at a temperature of 400°C for 2h;

[0074] 2), weigh 8.2g 50% Mn(NO 3 ) 2 solution, dissolved in 50g of deionized water, and uniformly impregnated on 50g of 200-mesh active component CaO, dried at 110°C for 2h, and then decomposed in a muffle f...

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Abstract

The invention provides a novel material for integrated desulfurization, denitrification and CO removal of flue gas, belonging to the technical field of flue gas purification. The novel material comprises the following components in parts by weight: 30-80 parts of an active component, 0.1-5 parts of a catalytic component A, 0.1-5 parts of a catalytic component B, 0.1-5 parts of an auxiliary agent and 2-30 parts of a carrier, wherein the active component is one or two selected from the group consisting of CaCO3, CaO and Ca(OH)2; the catalytic component A is one or more selected from the group consisting of Fe2O3 and Co3O4; the catalytic component B is one or more selected from the group consisting of MnO2, CuO and MoO3; the auxiliary agent is one or more selected from the group consisting ofMgO, CeO2, BaO and TiO2; and the carrier is one or more selected from the group consisting of kaolin, bentonite, gypsum and cement. The invention also provides a preparation method for the novel material used for integrated desulfurization, denitrification and CO removal of flue gas. The material is low in raw material cost and good in desulfurization, denitrification and CO removal effects, andhas a use temperature of 100-250 DEG C. The novel material is suitable for simultaneously removing SO2, SO3, NOX and CO in industrial exhaust gas such as blast furnace gas, converter gas and the like,and achieves the ultralow emission standard.

Description

technical field [0001] The invention belongs to the technical field of flue gas purification, and specifically relates to a new material integrating flue gas desulfurization, denitrification and CO removal, and its preparation and application. Background technique [0002] NO x and SO 2 It is one of the main pollutants in the atmosphere. It causes a series of hazards such as acid rain and photochemical smog, which seriously affects the ecological environment and human health. my country is a country with rich coal resources, and the flue gas produced by coal burning is NOx and SO 2 major source of emissions, so lower NO x and SO 2 Emission is the top priority of pollution reduction in my country. In addition, due to insufficient combustion, part of the flue gas is not completely oxidized, and the exhaust gas contains some CO. With the improvement of national emission standards, the treatment of CO will gradually be put on the agenda. For a part of the flue gas (such as...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/81B01D53/86B01D53/60B01D53/62
CPCB01D53/60B01D53/62B01D53/81B01D53/8637B01D53/864B01D2251/404B01D2251/602B01D2251/604B01D2251/606B01D2255/2073B01D2255/20738B01D2255/20746B01D2255/20761B01D2255/20769B01D2257/502B01D2258/0283Y02A50/20
Inventor 苏敏赵丹张明胜胡洧冰李启强乔莎颜智
Owner SOUTHWEST RES & DESIGN INST OF CHEM IND