Flame retardant mixture, its preparation and use
一种混合物、阻燃剂的技术,应用在阻燃剂混合物领域,能够解决阻燃聚合物成型体机械强度性质弯曲强度、断裂伸长率降低等问题
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Embodiment 1
[0285] According to DE-A-10359815, a sodium diethylphosphinate solution was prepared with a P content of 7.71% by weight. 2652 g of this solution were charged and a mixture of 1348 g of aluminum sulfate solution, 70 mg of a 22% by weight iron(III) sulfate solution and deionized water was added at 80°C. The crystal suspension was filtered while hot through a suction filter and washed with hot water. The wet product of the filter was dried in a drying cabinet at 120° C. under a nitrogen atmosphere for about 18 hours, then it contained 0.2% by weight of residual moisture (RF) and 18 ppm of iron. Iron phosphinate co-precipitates with aluminum phosphinate.
[0286] The heat resistance and processing window (see table for both) exceed that of pure aluminum diethylphosphinate (Comparative Example 16).
Embodiment 2
[0288] According to DE-A-10359815, a sodium diethylphosphinate solution was prepared with a P content of 7.71% by weight. According to Example 1, this was processed by using 0.2 g of a 22% iron(III) sulfate solution to a product comprising 0.2 wt. % RF and 52 ppm iron. Iron phosphinate co-precipitates with aluminum phosphinate.
[0289] The heat resistance and processing window (see table for both) exceed that of pure aluminum diethylphosphinate (Comparative Example 16).
Embodiment 3
[0291] According to DE-A-10359815, a sodium diethylphosphinate solution was prepared with a P content of 7.71% by weight. According to Example 1, this was processed by using 3.9 g of a 22% solution of iron(III) sulfate to a product comprising 0.2% by weight of RF and 1015 ppm iron. Iron phosphinate co-precipitates with aluminum phosphinate.
[0292] The heat resistance and processing window (see table for both) exceed that of pure aluminum diethylphosphinate (Comparative Example 16).
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