High-abrasion-resistant anti-static electricity rolling needle and preparation method thereof

A needle rolling and coating technology, applied in jewelry, etc., can solve the problems of high defect rate of batteries, low Teflon hardness, and inability to eliminate static electricity, so as to reduce the possibility of adsorption on batteries and improve wear resistance The effect of improving performance and service life, improving yield and performance stability

Inactive Publication Date: 2020-09-04
ZHUHAI COSMX BATTERY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, because Teflon has low hardness and does not have wear resistance, it is necessary to replace Teflon frequently during the winding process, which affects the efficiency; in addition, during the winding process, the mutual friction between Teflon and the diaphragm is likely to generate large static electricity. It is very easy to absorb foreign dust or other impurities, which will cause a high defect rate of the battery cell and reduce the performance of the battery cell, etc.
[0004] In addition, the current improvement plan also includes coating a layer of nickel and Teflon on the surface of the steel coil needle, and the nickel layer and Teflon are independent layers, and the coating method can increase the two layers. The adhesiveness of the battery can improve the service life and reduce the frequency of replacement during the winding process, but it still cannot eliminate static electricity, and there is still a high risk of defective rate of the battery core

Method used

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  • High-abrasion-resistant anti-static electricity rolling needle and preparation method thereof

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preparation example Construction

[0057]

[0058] The present invention also provides a method for preparing the above-mentioned coating, the method comprising: preparing the coating by using the above-mentioned nickel-cobalt-polytetrafluoroethylene mixed plating solution.

[0059] In a preferred solution of the present invention, the method includes: preparing the plating layer by electroplating the above nickel-cobalt-polytetrafluoroethylene mixed plating solution.

[0060] In a preferred version of the present invention, the method comprises the steps of:

[0061] 1) preparing nickel-cobalt-polytetrafluoroethylene mixed plating solution;

[0062] 2) The element to be plated is used as a cathode plate, and pure nickel (purity ≥ 99.9%) is used as an anode plate for electroplating.

[0063] In a preferred solution of the present invention, the temperature of the electroplating is 40-70°C; the time of the electroplating is 10min-2h, and further, by adjusting the time of the electroplating, different thicknes...

Embodiment 1

[0082] Prepare 5L nickel-cobalt-polytetrafluoroethylene mixed plating solution, wherein the solvent in the mixed plating solution is water, and the following substances are also included in the mixed plating solution: nickel sulfate 300g / L, cobalt sulfate 40g / L, particle size 0.05 μm polytetrafluoroethylene 5g / L, buffering agent 25g / L, brightener 10mL / L, surfactant 0.5g / L, wherein the buffering agent is boric acid, brightening agent is 5g o-benzoylsulfonimide, 0.8 The mixed solution of g dihydroxydimethylacetylene, 100mL sodium vinyl sulfonate, the surfactant is sodium dodecyl sulfonate; the pH of the mixed plating solution is 3.5;

[0083] Coating preparation: Take high-carbon and high-chromium alloy steel coil needle as the cathode plate, the size is 245mm long * 8.5mm wide * 8mm thick, pure nickel (purity ≥ 99.9%) is the anode plate, the size is 255mm * 10mm wide * 8mm thick , the temperature of the electroplating process is 55°C, and the current density is 6A / dm 2 , The e...

Embodiment 2

[0085] Prepare 5L nickel-cobalt-polytetrafluoroethylene mixed plating solution, wherein the solvent in the mixed plating solution is water, and also includes the following substances in the mixed plating solution: nickel sulfate 200g / L, nickel chloride 40g / L, cobalt sulfate 50g / L, polytetrafluoroethylene with a particle size of 0.08μm 8g / L, buffering agent 15g / L, brightener 15mL / L, surfactant 1.0g / L, wherein the buffering agent is phosphoric acid, and the brightening agent is 10g o-phthalic acid A mixed solution of acylsulfonimide, 3g dihydroxydimethylacetylene, and 150mL sodium vinylsulfonate, and the surfactant is sodium dodecylsulfonate; the pH of the mixed plating solution is 4.0;

[0086] Coating preparation: Take high-carbon and high-chromium alloy steel coil needles as the cathode plate, the size is 245mm long * 8.5mm wide * 8mm thick, pure nickel (purity ≥ 99.9%) plate is used as the anode plate, the size is 255mm * 10mm wide * 8mm thick, the temperature of the electro...

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Abstract

The invention provides a high-abrasion-resistant anti-static electricity rolling needle and a preparation method thereof. A nickel-cobalt-polytetrafluoroethylene mixed bathing solution is deposited ona rolling needle matrix through an electroplating manner; in the production process, the rolling needle is applied, compared with a steel layer or a pure nickel layer, the nickel-cobalt alloy has higher intensity and higher hardness, so that the wear resistance and the service life of the rolling needle are greatly improved; polytetrafluoroethylene in a coating has high-lubrication low-friction performance, so that the friction between the rolling needle and a separation film can be greatly reduced, and the defective fraction of battery cells caused in the drawing process of the rolling needle is effectively reduced; and nickel-cobalt has conductivity, so that static electricity brought by the own separation film and static electricity generated in the rolling process can be eliminated through the nickel-cobalt-polytetrafluoroethylene coating on the surface of the rolling needle, the possibility that dust or other impurities and foreign matter are adsorbed to the battery cells is reduced, the yield and the performance stability of the battery cells are improved.

Description

technical field [0001] The invention relates to the technical field of lithium battery production and related equipment and devices, in particular to a high wear-resistant and anti-static rolling needle and a preparation method thereof. Background technique [0002] The production of lithium batteries generally includes steps such as batching, coating, sheet making, winding, packaging, liquid injection, chemical formation, secondary sealing, and sorting and volume separation. As one of the most critical steps in the manufacturing process of lithium batteries, winding has an extremely important impact on the safety performance and life of the battery. The winding main equipment device is a winding needle, which is divided into upper and lower winding needles. There is a gap between the upper and lower winding needles, and the diaphragm is clamped through the gap. Under the traction of the diaphragm, the winding of the positive electrode, diaphragm, and negative electrode is r...

Claims

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Application Information

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IPC IPC(8): C25D3/56C25D7/00
CPCC25D3/562C25D7/00
Inventor林文荣李素丽裴佳佳李俊义徐延铭
OwnerZHUHAI COSMX BATTERY CO LTD