Compound, display panel and display device
A compound and independent technology, applied in the field of display panels and display devices, compounds, can solve the problem of low luminous efficiency
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Embodiment 1
[0175] Embodiment 1: the preparation of compound H1
[0176] (1)
[0177] Under a nitrogen atmosphere, add about 100mL of anhydrous toluene to a 250mL reaction flask, then sequentially add compound A1 (4mmol), compound a1 (4mmol), sodium tert-butoxide t-BuONa (10mmol), catalyst tris(dibenzylideneacetone ) Dipalladium Pd 2 (dba) 3 (0.2mmol) and the ligand 2-bicyclohexylphosphine-2',6'-dimethoxybiphenyl S-Phos (0.6mmol), heated to 110°C and reacted overnight. After the reaction is complete, cool to room temperature, add dichloromethane DCM / H 2 O was extracted, and the collected organic phase was washed with anhydrous Na 2 SO 4 After drying, the filtrate was collected by suction filtration, the solvent was spun off and purified by column chromatography to obtain intermediate compound B1 (yield 80%).
[0178] MALDI-TOF (m / z): C31H20BrN: Calculated: 485.08, Found: 485.30.
[0179] (2)
[0180] Under a nitrogen atmosphere, compound B1 (1 mmol) was added to anhydrous tetr...
Embodiment 2~10
[0187] Embodiment 2~10: the preparation of compound H2~H10
[0188] The difference between the preparation method of compounds H2-H10 and that of Example 1 is that one or more of the raw material compounds C1 and c1 in step 3 were replaced to finally obtain the corresponding compounds, see Table 1 for details.
[0189] The raw material compounds C2 and C3 in Table 1 were prepared by referring to the preparation method of compound C1.
[0190] The difference is: in the preparation of compound C2, compound b1 is replaced by b2. The yield of compound C2 was 65%. MALDI-TOF (m / z): C44H27NS: Calculated: 601.19, Tested: 601.40.
[0191]
[0192] In the preparation of compound C3, compound b1 was replaced by b3. The yield of compound C3 was 63%. MALDI-TOF (m / z): C50H32N2: Calculated: 660.26, Tested: 660.45.
[0193]
[0194] Table 1: Synthetic parameters of compounds H2-H10
[0195]
[0196]
[0197] Simulated calculation of energy levels of compounds: using density ...
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