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A silicon-doped cerium element infrared detector, preparation method and system

An infrared detector and silicon doping technology, which is applied in the manufacture of electrical components, semiconductor devices, and final products, can solve the problems of difficult integration of indium gallium arsenide detectors, toxic raw materials, high cost, etc.

Active Publication Date: 2022-08-02
HUBEI UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, it is precisely because of the small band gap that the photodetectors made of these materials have a large leakage current with the increase of temperature, resulting in a low detection rate at room temperature.
At the same time, the performance of germanium detectors is limited by its high dark current, InGaAs detectors are difficult to integrate into silicon-based chips or devices, and the cost of these two materials is high
[0003] On the other hand, MCT (Mercury Cadmium Telluride) detectors dominate the mid-infrared market due to their high performance, but they also face the problems of toxic raw materials, the need to work at ultra-low temperatures to achieve high detection rates, and the need for associated silicon-based readout chips. problems, which lead to its high cost

Method used

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  • A silicon-doped cerium element infrared detector, preparation method and system
  • A silicon-doped cerium element infrared detector, preparation method and system
  • A silicon-doped cerium element infrared detector, preparation method and system

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preparation example Construction

[0037] figure 2 It is a flow chart of the preparation method of the silicon-doped cerium element infrared detector of the present invention. like figure 2 As shown, a preparation method of a silicon-doped cerium element infrared detector includes:

[0038] Step 101 : implanting arsenic into the back surface of the silicon wafer as an N-type semiconductor of the diode by ion implantation, and annealing at 1000° C. for 20s. The arsenic element adopts 2.0×10 15 cm -2 @30keV.

[0039] Step 102 : implanting boron element on the front side of the silicon wafer as a P-type semiconductor of the diode by means of ion implantation, and then injecting cerium element five times into the depletion layer of the P-type semiconductor to form a 1-micron-thick cerium ion implantation layer, By annealing at 1050°C for 10s. The boron element adopts 10 15 cm -2 @30keV. The cerium element is in accordance with 2.5×10 13 cm -2 @2MV; 1.6×10 13 cm -2 @1.4MV; 1.2×10 13 cm -2 @0.95MV; 9...

Embodiment example 1

[0053] Raw materials: silicon wafer, cerium element, boron element, arsenic element, high-purity aluminum particles, methanol, acetone, isopropanol, deionized water, hydrofluoric acid, toluene, black wax, nitric acid, potassium hydroxide and sodium carbonate.

[0054] Arsenic (2.0×10) was implanted into the backside of the silicon wafer by ion implantation 15 cm -2 @30keV) as the N-type semiconductor of the diode and annealed by a rapid thermal annealing furnace at 1000°C for 20s. Boron (10) is implanted on the front of the silicon wafer by ion implantation 15 cm -2 @30keV) as the P-type semiconductor of the diode, and then inject cerium element (2.5×10 13 cm -2 @2MV; 1.6×10 13 cm -2 @1.4MV; 1.2×10 13 cm -2 @0.95MV; 9×10 12 cm -2 @0.6MV; 6×10 12 cm -2 @0.35MV) to the depletion layer, forming a uniform cerium ion implantation layer with a thickness of 1 μm, with a bulk density of 1.6×10 16 cm -3 , and finally annealed at 1050 °C for 10 s in a rapid thermal anneali...

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Abstract

The invention relates to a silicon-doped cerium element infrared detector, a preparation method and a system. The method includes: implanting arsenic into the back of the silicon wafer as an N-type semiconductor of the diode, and annealing at 1000° C. for 20s; implanting boron on the front of the silicon wafer as a P-type semiconductor of the diode, Inject five times of cerium into the depletion layer of the P-type semiconductor, anneal at 1050°C for 10s; etch away the silicon dioxide on the surface of the silicon wafer by hydrofluoric acid, and put the silicon wafer into a vacuum coating The front and back electrodes are plated in the instrument, and then taken out and annealed at 360°C for 2mins in a rapid thermal annealing furnace; the silicon wafers are cut into individual devices; the etching surface is polished by soaking in 80°C potassium hydroxide solution for 2mins to remove black Wax gets detectors. The invention has a high detection rate in the mid-infrared field at low temperature, and pushes the detection field of the silicon-based photodetector to the near and mid-infrared bands.

Description

technical field [0001] The invention relates to the field of preparation of infrared detectors, in particular to a silicon-doped cerium element infrared detector, a preparation method and a system. Background technique [0002] Silicon-based photodetectors are the main choice in the near-ultraviolet, visible, and ultra-near-infrared spectroscopy fields, but limited by the band gap width, the cut-off wavelength is 1.1 μm, which makes silicon-based photodetectors unsuitable for longer wavelength near-infrared photodetectors. , In the field of mid-infrared, it also includes the commonly used communication band: 1.3μm ~ 1.55μm. This field is occupied by detectors of narrow-bandgap semiconductor materials, such as germanium or indium gallium arsenide. However, it is precisely because of the smaller band gap that the photodetectors prepared from these materials have a larger leakage current with the increase of temperature, resulting in a lower detection rate at room temperature....

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L31/101H01L31/103H01L31/0368H01L31/18
CPCH01L31/101H01L31/103H01L31/03682H01L31/1804Y02P70/50
Inventor 凯文·彼得·霍梅伍德周诗豪玛侬·达松桑·洛伦索高云李荣夏晓红
Owner HUBEI UNIV