Prepn of guanidyl thiocyanate
A technology of guanidine thiocyanate and ammonium thiocyanate, which is applied in chemical instruments and methods, preparation of organic compounds, organic chemistry, etc., can solve the problem that the product purity is not very high, and achieve good quality, high purity, simple and practical process Effect
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[0016] A preparation method of guanidinium thiocyanate, which has the following process flow: a, putting guanidine carbonate and ammonium thiocyanate with a weight ratio of 2:1 into a reactor, and reacting for 2 hours at 50-90° C. to obtain thiocyanate Crude guanidine;
[0017] B, dissolving, at normal temperature, the guanidine thiocyanate crude product is dissolved in water in a ratio of 1:1 by weight;
[0018] c. Filtration, to remove impurities such as raw materials and reaction by-products by filtration;
[0019] d, dehydration, the mother liquor after filtering is dehydrated at high temperature;
[0020] e, crystallization, cooling the supersaturated solution, concentrating and crystallizing, and obtaining guanidine thiocyanate with a purity greater than 99%.
[0021] Further: the guanidinium thiocyanate after the e step is passed through b, c, d, e steps again, wherein in the b step, the weight ratio with water is 1: 1, in order to obtain the guanidine thiocyanate wit...
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