Monox-alumina containnig hydrocracking catalyst

A silicon oxide-containing, hydrocracking technology, applied in hydrocarbon oil cracking, petroleum industry, etc., can solve the problem of low hydrocracking activity, and achieve the effect of improved hydrocracking activity and good selectivity

Inactive Publication Date: 2006-06-28
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Although the hydrocracking catalysts containing silica-alumina provided by the prior art can meet the requirements of some hydrocracking reactions, their hydrocracking activity is still low

Method used

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  • Monox-alumina containnig hydrocracking catalyst
  • Monox-alumina containnig hydrocracking catalyst

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0046] 800 grams of NaY molecular sieve (SiO 2 / Al 2 O 3 = 4.8, the crystallinity is defined as 100%, the product of Changling Refinery) was placed in 4000 ml of ammonium chloride (product of Beijing Chemical Factory, analytically pure) aqueous solution with a concentration of 1.0 mol, exchanged at 90 ° C for 1 hour under stirring, Filtered, washed with deionized water until no chloride ion was detected, dried at 120°C, and calcined at 550°C for 4 hours. Repeat the above process twice to obtain the Y-type molecular sieve A of the sodium content (calculated as sodium oxide) 0.35% by weight (measured by flame atomic absorption spectrometry), and the sample crystallinity measured by X-ray diffraction method is 76%, and the Y-type molecular sieve A is obtained. 200 grams were placed in 1000 milliliters of ammonium fluoride (Beijing Chemical Factory product, analytically pure) aqueous solution with a concentration of 0.2 mol, stirred at room temperature for 1 hour, filtered, drie...

example 2

[0048] Weigh 12 grams of disordered Y-type molecular sieve B in Example 1 and mix with 100 grams of SB powder (gibbsite produced by Condea, Germany) to obtain Si-2, the precursor of silica-alumina (74% by weight on a dry basis) , Si-2 was calcined at 550 °C for 4 hours, and its X-ray diffraction pattern was shown in figure 1 b, silicon oxide content and k value are shown in Table 1

example 3

[0050] Synthesize rare earth-containing five-membered ring structure zeolite according to Example 12 in CN1020269C to obtain rare earth-containing five-membered ring structure zeolite D; and synthesize partially crystallized rare earth-containing five-membered ring structure zeolite E according to the exact same conditions except that the crystallization temperature is 90°C. The rare earth-containing five-membered ring structure zeolite E has a silica content of 93.3% by weight, an alumina content of 4.5% by weight, RE 2 O 3 1.5% by weight (RE 2 O 3 Represents rare earth oxides, in which lanthanum oxide accounts for 26 wt% of the total rare earth oxides, ceria accounts for 51 wt% of the total rare earth oxides, and other rare earth oxides account for 23 wt% of the total rare earth oxides). The crystallinity of the partially crystallized ZSM-5 molecular sieve E was determined to be 6% based on the rare earth-containing five-membered ring structure zeolite D.

[0051] Take 15...

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Abstract

A hydrocracking catalyst containing Si-Al oxides contains two molecular sieves, one's metal components selected from Fe, Co or Ni of VIII family, at least one of them, and another's selected from Mo or W of VIB family, at least one of them. Its K value is 0.4 - 15A.(cm2.g)-1. One molecular sieve with octahedral zeolite structure with the content of Si-Al oxides of 10 - 90wt% of the catalyst, and another's limiting exponential is 0.5 C10G 47 / 20 1 15 3 2003 / 5 / 30 1552818 2004 / 12 / 8 1261542 2006 / 6 / 28 2006 / 6 / 28 2006 / 6 / 28 SINOPEC Beijing 100029 Shi Jianwen Nie Hnog Mao Yichao xu shu pang lizhi 72001 The Company Ltd. of the Chinese Patent Agency (Hong Kong) Zi Building 22, Yingjun Centre, No.23, Gangwan Road, Hong Kong Wanzi

Description

technical field [0001] The present invention relates to a hydrocracking catalyst, and more particularly to a silica-alumina-containing hydrocracking catalyst. Background technique [0002] In recent years, the tendency of crude oil to become heavier and inferior in the world has become increasingly obvious. At the same time, the demand for middle distillates and reforming and steam cracking feedstocks has continued to increase, which promotes the use of high-quality and light heavy distillates Hydrocracking technology for chemical purposes has been developed rapidly, and hydrocracking catalyst is one of the most important and key factors. [0003] Hydrocracking catalyst is a dual-function catalyst, it has both hydrogenation activity and cracking activity, that is, it contains both hydrogenation active components and acidic components. The hydrogenation active components are generally selected from VIB and VIII in the periodic table of elements. Gr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G47/20
Inventor 史建文聂红毛以朝石亚华李大东王奎熊振霖张晓辉
Owner CHINA PETROLEUM & CHEM CORP
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