Oil/grease-and water sizing agent for treatment of cellulosic materials

A technology of sizing agent and cellulose, which is applied in the directions of adding water repellent, adding non-fiber pulp, and processing fiber raw materials to achieve high-efficiency performance.

Inactive Publication Date: 2005-07-27
SOLENIS TECH CAYMAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0015] Consequently, much work has been done to develop materials for efficient oil / grease sizing and efficient water sizing of cellulosic products, but these efforts only partially address the desired combination of sizing properties

Method used

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  • Oil/grease-and water sizing agent for treatment of cellulosic materials
  • Oil/grease-and water sizing agent for treatment of cellulosic materials
  • Oil/grease-and water sizing agent for treatment of cellulosic materials

Examples

Experimental program
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Embodiment

[0557] Examples: The numbers indicate the corresponding examples in the synthesis examples.

[0558] R F Equivalent: This column represents R in each monomer or polyamine unit F The molar mass of the group. This also indicates the number of J groups. R in each monomer unit F The molar amount of a group is also indicated by "r".

[0559] Epichlorohydrin Equivalent: This column represents the molar amount relative to the polyamine.

[0560] n: CH between amine nitrogen atoms 2 number of groups.

[0561] m: the number of repeating amine groups in structural formula I; the total number of amine groups is m+1.

[0562] R F Type: The type of the fluorinated group. In the preferred reaction mode, it is R on the fluoroepoxide F Substituents.

[0563] A: The group in formula III, J.

[0564] p: number of A groups in formula III, J.

[0565] r / N: The ratio of r groups to the total number of nitrogen atoms in the polyamine.

[0566] epi / N: Ratio of epichlorohydrin groups to...

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Abstract

A water-dispersible oil / grease-sizing and water-sizing agent that provides oil / grease and water-sizing for paper and other cellulosic materials. The agent works effectively for both oil / grease and water sizing at high temperatures. The polymeric agent's key features include a polyamine component which is a repeating monomer unit with cellulose-reactive and fluorinated groups substituted on the polyamine.

Description

technical field [0001] The present invention relates to the improvement of oil / grease and water sizing of cellulosic materials, especially paper products. In particular, the present invention relates to selected polyamines substituted with cellulose-reactive fluorocarbon groups. Background technique [0002] Highly effective compounds or polymers that provide oil / grease and water sizing properties to paper have long been desired. Many grades of paper need to be resistant to both oil / grease and water. The currently commercially available chemical that is said to provide both oil / grease sizing and water sizing properties is not actually a highly effective water sizing agent. When both a high level of oil / grease resistance and a high level of water resistance are required, a separate water sizing must be added with the oil sizing. Oil / grease sizing and water sizing often have a negative impact on each other's performance, so when both oil / grease and wa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G73/04C08G73/02D21H17/56D21H21/16
CPCC08G73/0213D21H17/56C08G73/022D21H21/16
Inventor 凯尔·博托夫
Owner SOLENIS TECH CAYMAN
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