Flexible polyurethane foam
A foam and polyurethane technology, applied in the field of flexible polyurethane foam, can solve the problems of insufficient load characteristics of flexible polyurethane foam, hysteresis of foam properties, deterioration of relative compression set characteristics, and low density
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Examples
Embodiment 1
[0064] Prepare a kind of polyisocyanate composition with following method: the MDI (containing 50 weight % 4,4 '-MDI and 50 weight % 2,4'+2,2 '-MDI) of 84.3 weight parts with 15.7 weight parts (pbw ) of polymeric MDI (NCO value 30.7% by weight and containing 35.4 pbw of 4,4`-MDI, 2.3 pbw of 2,4`+2,2`-MDI and 62.3 pbw of isocyanate functionality of 3 or higher homologues) mix.
[0065] A polyol composition was prepared as follows: 36.2 pbw of Arcol 1374, 9.4 pbw of Daltocel F526, 2.9 pbw of water, 0.24 pbw of EPk-38-1, a surfactant from Goldschmidt, 0.34 pbw of A mixture of Irganox 1135 and Irgafos TNPP (50 / 50, w / w) (both antioxidants ex Ciba) was mixed.
[0066] Measurement methods
Embodiment 2
[0069] First, the difference in particle size is significant (compare figure 1 , 3 and 5). exist figure 1 Large particles with sharp boundaries can be seen in ; in image 3 The middle particles are very small and in Figure 5 The middle boundary is not so sharp, and the PHD material seems to form aggregates without clearly defined boundaries.
[0070] Secondly, figure 1 and 2 Good representation of broken particles at the fracture surface of the foam struts. Figure 3-6 Shows no breakage of the particulate material.
Embodiment 3
[0072] In an open 101 bucket mix the following: 58 pbw of Daltocel F428, 30 pbw of polyol X, 12 pbw of Daltocel F526, 7 pbw of water, 1.2 pbw of B4113 (a surfactant from Goldschmidt), 0.6 pbw of D8154 ( an amine catalyst from Airproducts), 0.1 pbw of Niax Al (a catalyst from Union Carbide) and 0.3 pbw of D33 LV (a catalyst from Airproducts). To this was added 110 pbw of the 4:1 by weight mixture of MDI and polymeric MDI used in Example 1. The index is 100. The mixture was allowed to react. A flexible foam containing open cells is obtained with a free rise density of 19kg / m 3 .
[0073] Polyol X is a polyoxyethylene polyoxypropylene polyol having a nominal functionality of 3, an average equivalent weight of approximately 2000, an EO content of 28 wt. %, an EO end-capped content of 15 wt. %, and the remainder of EO with random distribution of PO; primary hydroxyl content about 85% and monohydroxyl (momool) content about 12 mole%.
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Abstract
Description
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