The invention provides a metal corrosion inhibitor composition, a metal corrosion inhibitor thereof and an application thereof. The metal corrosion inhibitor composition contains a water-soluble inorganic zinc salt, an organic phosphine compound, an inorganic phosphorus compound, polyepoxysuccinic acid, a polyacrylamide polymer, and a gluconate, wherein the weight ratio is 0.5-5:0.1-5:0.1-2.5:0.5-8:3-20:1. The metal corrosion inhibitor of the invention has the advantages of good water solubility, and easy complex use with other water processing agents, can satisfy anticorrosion requirements of various metal devices (such as copper devices), and also can satisfy requirements of carbon steel devices of a system, so the metal corrosion inhibitor has very high industrial application values.