The invention relates to the technical field of
high polymer materials, in particular to intrinsic
flame-retardant phenoxy amine resin and a synthesis method thereof. The resin is synthesized from polybasic primary amine, an
aldehyde compound, a
phosphorus-
hydrogen-bond-containing compound and polyfunctional aromatic
epoxy resin, n (NH2): n (
aldehyde compound): n (
phosphorus-
hydrogen-bond-containing compound) is controlled to be 1: (1.05-2.00): 1, and the
polymer resin is obtained through
aldehyde-amine
condensation reaction,
phosphorus-
hydrogen addition reaction and
epoxy group ring-opening reaction chain extension. The phenoxyamine resin is mild in synthesis process condition and high in chain growth
controllability, a
polymer chain contains a large number of phosphorus-containing
flame-retardant elements, and the phenoxyamine resin has intrinsic
flame-retardant performance, achieves V-0-level flame retardance, has the limit
oxygen index of 30% or above, the glass-
transition temperature of 150 DEG C or above, the tensile strength of 75 MPa or above and the bending strength of 180 MPa or above. The material can be molded through a plurality of processes such as mold pressing, injection molding and solution
coating, and is a novel material which is suitable for the fields of
electronic packaging,
rail transit,
aerospace and the like and has strict requirements on flame retardance, adhesion and structural
bearing capacity.