The invention provides a
selenium-containing
wastewater treatment method, and belongs to the technical field of
wastewater treatment. The treatment method comprises the following steps: adjusting the pH value of the
selenium-containing
wastewater to 7-10, adding an organic-inorganic composite flocculant, carrying out stirring reaction, and carrying out
solid-liquid separation to obtain primarily treated wastewater; introducing the primarily treated wastewater into a
tower oxidation reactor for
ozone oxidation reaction to oxidize tetravalent
selenium into hexavalent selenium; the wastewater subjected to
ozone oxidation is adjusted to be weakly acidic and then flows through a
manganese sand filter, and selenium in the wastewater is adsorbed by
manganese sand; wherein in the
tower-type oxidation reactor, the wastewater and
ozone gas are subjected to gas-liquid countercurrent
contact reaction and then subjected to standing reaction. According to the method, three-stage processes are set, including
flocculation and
sedimentation of an organic and inorganic composite flocculant, step-by-step oxidation of ozone,
filtration and adsorption of
manganese sand under weak acidity, and efficient oxidation of selenite (tetravalent selenium) into
selenate (tetravalent selenium), so that the selenium removal efficiency is improved, and the removal rate of selenium in selenium-containing wastewater reaches up to 99% or above.