This invention relates to a multifunctional bioactive dental bulk filling composite resin and its preparation method. The composite resin comprises an organic
resin matrix and an
inorganic filler; the organic
resin matrix comprises polymerizable resin monomers and a
photoinitiator system, the polymerizable resin monomers comprising dimethacrylate monomers and E-POSS; the
inorganic filler comprises nMgO and sSiO2 with a silanized surface. The preparation method includes the following steps: preparing nMgO
powder using a
sol-
gel method combined with a gradient
calcination process; preparing submicron-sized sSiO2 using the Stöber method and subjecting it to surface
silanization treatment to obtain silanized sSiO2; mixing the polymerizable resin monomers, E-POSS, and the
photoinitiator system, stirring in the dark until a homogeneous
resin matrix is formed; adding the obtained nMgO and silanized sSiO2 to the resin matrix in a specific ratio and mixing and dispersing evenly to obtain an uncured paste-like composite resin.