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Acrylic acid series non-aqueous dispersoid

A non-aqueous dispersion, acrylic technology, used in polyurea/polyurethane coatings, coatings, etc., can solve the problems of heavy paint odor, short service life of wall coatings, prolonged construction period, etc., and achieve environmental and human toxicity. The effect of reducing, good high temperature resistance and good low temperature construction performance

Inactive Publication Date: 2008-10-29
CNOOC CHANGZHOU PAINT & COATINGS IND RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For exterior wall coatings prepared with strong solvent-based acrylic resin, the old coating film on the wall body needs to be removed first when the exterior wall is refurbished, otherwise it is easy to cause bottoming phenomenon, resulting in uneven appearance of the new coating film; during construction, the coating smells heavy, It causes great harm to the construction personnel and the environment; the construction solid content of the coating is not high enough, the emission of volatile organic compounds (VOC) is relatively large, and the photochemical pollution of the solvent is relatively serious, which is not environmentally friendly
All in all, the current exterior wall coatings have the disadvantages of easy peeling of the coating film, serious pollution, and short service life of the wall coating film, especially not suitable for construction in winter, and it is not suitable for construction when the wall surface is not completely dry. prolong the construction period

Method used

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  • Acrylic acid series non-aqueous dispersoid
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  • Acrylic acid series non-aqueous dispersoid

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] (1) Preparation of dispersion stabilizer

[0024] See Table 1 for the raw material monomer formula of synthetic dispersion stabilizer;

[0025] The solvent used as the dispersion medium is: 340g heptane, 240g aliphatic hydrocarbon solvent with a boiling point of 145-200°C, 50g ethyl acetate, 90g Solvesso-100 heavy aromatic hydrocarbon solvent;

[0026] Table 1

[0027] Monomer

Styrene (propylene

Acrylic acid copolymer

with monomer)

Acrylic hydroxyl

ethyl ester

(containing hydroxyl

functional monomer)

Methacrylic

Acid (carboxyl-containing

functional monomer)

Methacrylic

isobutyl ester

(acrylic acid copolymer

common monomer)

Methacrylic

Acid 2-ethyl

Hexyl ester (propylene

acid or methacrylic acid

8-18 of enoic acid

carbon alkyl ester)

weight, g

320

80

17

190

252

Wt%

37.25

9...

Embodiment 2

[0038] (1) Preparation of dispersion stabilizer

[0039] The formula of raw material monomers used to synthesize dispersion stabilizer is shown in Table 3;

[0040] The solvent used as the dispersion medium is: 51g ethyl acetate, 600g aliphatic hydrocarbon with a boiling point of 145-200°C, 80g xylene;

[0041] table 3

[0042] Monomer

Styrene (propylene

Acrylic acid copolymer

with monomer)

Acrylic hydroxyl

Ethyl ester (containing hydroxyl

base functional unit

body)

Methacrylic

Acid (carboxyl-containing

functional monomer)

Acrylic iso

Octyl (acrylic acid

or methacrylic acid

8-18 carbon alkane

base ester)

Methacrylic

Acid 2-ethyl

Hexyl ester (propylene

acid or methacrylic acid

8-18 of enoic acid

carbon alkyl ester)

weight, g

375

84

12

182

120

Wt%

48.51

10.87

1.5...

Embodiment 3

[0053] (1) Preparation of dispersion stabilizer

[0054] The ratio of raw material monomers used to synthesize dispersion stabilizers is shown in Table 5;

[0055] The solvent used as the dispersion medium is: 71g ethyl acetate, 320g 200# solvent gasoline, 240g aliphatic hydrocarbon with a boiling point of 145-200°C, 96g xylene;

[0056] table 5

[0057] Monomer

Styrene (propylene

Acrylic acid copolymer

with monomer)

Acrylic hydroxyl

Ethyl ester (containing hydroxyl

base functional unit

body)

Methacrylic

isooctyl

(acrylic or methacrylic

Acrylic

8-18 carbon alkyl

ester)

Methacrylic

isobutyl ester

(acrylic acid copolymer

common monomer)

Methacrylic

Acid (containing carboxyl

functional monomer)

weight, g

204

72

144

338

17

Wt%

26.32

9.29

18.58

43.63

2.19

...

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Abstract

The invention discloses a non-aqueous dispersant of acrylic acid series for double-component polyurethane paint with hydroxy component, which comprises the following parts: dispersing stabilizer, dispersing phase and dispersing dielectric with the molar rate of dispersing stabilizer and dispersing phase at (3-4):(6-7) and 50-70wt% solid content in the non-aqueous dispersant, wherein the dispersing stabilizer possesses linear acroleic acid polymer with active insaturated and double-bond; the content of hydroxyl group is 1-3wt% with glass transition point at -13-+15 deg.c; the weight average molecular weight is 16000-18000; the dispersing phase is gelatinized acroleic acid polymer with the grain size of gel particle at 0.2-0.8um; the glass transition point is 25-55 deg.c with hydroxyl group at 1-3wt%; the dispersing dielectric is composite solvent of aliphatic hydrocarbon and aromatic and ester solvent with at least 80wt% aliphatic hydrocarbon solvent.

Description

technical field [0001] The present invention relates to an acrylic non-aqueous dispersion particularly suitable as a hydroxyl component for two-component polyurethane coatings. Background technique [0002] In recent decades, water-dispersible acrylic or acrylate resin emulsions have been widely used to formulate architectural exterior paints. Although this resin emulsion has strong adhesion and good weather resistance, the life of the wall coating film prepared with it is generally 3 to 5 years, which is still not ideal. . For exterior wall coatings prepared with strong solvent-based acrylic resin, the old coating film on the wall body needs to be removed first when the exterior wall is refurbished, otherwise it is easy to cause bottoming phenomenon, resulting in uneven appearance of the new coating film; during construction, the coating smells heavy, It causes great harm to the construction personnel and the environment; the construction solid content of the coating is n...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L33/02C09D175/04
Inventor 陈月珍丁帮勇钱伯容潘玉红王红岩
Owner CNOOC CHANGZHOU PAINT & COATINGS IND RES INST