The present invention provides a glass substrate and a preparation method thereof, and an electronic device. The glass substrate includes: a bottom layer, a top layer, a glass plate laminate, and a glass bonding laminate. The glass plate laminate includes m glass plate single
layers, and the glass bonding laminate includes m+1 glass bonding single
layers. The melting points of the glass bonding single
layers are lower than the melting points of the glass plate single layers. The glass bonding single layer includes glass
powder and an organic
adhesive with a content of 70%-85%. The glass
powder is made using special process steps. In the present application, the glass bonding single layer has a
low melting point, a low
glass transition point, and high uniformity, and the raw materials are inexpensive, rich in sources, low in synthesis temperature, and simple in process, which is conducive to industrial production. The glass bonding single layer has a lower
thermal expansion coefficient, higher strength, better
chemical stability and
thermal stability, and has a high bonding force with high
borosilicate glass and
microcrystalline glass, and the glass bonding single layer has good insulation and higher safety.