This invention relates to a method for modeling the curing
kinetics of
polymer resins, specifically providing a method for fitting the curing
kinetics of
polymer resins based on a segmented model. The method employs a three-stage segmented
kinetic model. In the first stage, an external catalytic model is introduced to quantify the inductive acceleration effect of the co-catalyst in the early stages of the reaction. In the second stage, the Kamal-Sourour model is used to ensure the fitting accuracy of the
chemical control region. In the third stage, a
diffusion correction term based on thermodynamic evolution is introduced to quantify the
diffusion resistance caused by entering the glassy state in the later stages, significantly improving the fitting accuracy at the end of curing. More importantly, this invention creatively proposes a method based on the
activation energy minimum point. α tr and dynamic
glass transition point α vit The segmentation points effectively couple the external catalytic model, the Kamal-Sourour model, and the dynamic
diffusion model, effectively solving the problem of inaccurate fitting of the full-cycle
kinetics, improving the fitting accuracy, and providing data support for the fine-tuning of the curing process.