Alcohol water-soluble resin and method for making same

A water-soluble resin and hydrophilic technology, which can be used in pharmaceutical formulations, organic active ingredients, monocarboxylate copolymer adhesives, etc., can solve problems such as cost increase and environmental pollution, and achieve the effect of reducing solvent costs

Active Publication Date: 2008-06-25
常熟国和新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Resin is the main raw material for the production of fine chemical products such as inks, adhesives, and coatings. Resin determines the performance, cost, and solvent dilution of these products; currently, most of the resins used to produce the above products are based on benzene, Diluted with ketone solvents, these solvents not only seriously pollute the environment, but also because they are petroleum refined products, with the rise of petroleum prices, the cost rises sharply; due to the pressure of cost and environmental protection, there are various systems in the market. Esters are resins used as solvents, wherein the applicant of the present invention describes a method of producing alcohol-soluble resins with vinyl acetate as the main raw material in another invention application "A kind of alcohol-soluble resin and its preparation method" (application number 200510021271. However, whether it is esters or alcohols, although their toxicity is lower than that of benzenes and ketones, they still belong to the scope of organic solvents. Resin as a solvent, that is, alcohol water-soluble resin or water-soluble resin, minimizes the amount of organic solvents, and becomes one of the goals pursued by the resin industry
There is no relevant report on the production of alcohol water-soluble resin by formula or process similar to the present invention

Method used

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  • Alcohol water-soluble resin and method for making same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] The preparation of embodiment 1 alcohol water-soluble resin of the present invention

[0032] Equipment: The equipment required by the present invention is: a reaction kettle equipped with a stirrer, a reflux condenser, a stainless steel dropping tank, a heating and a temperature controller.

[0033] ①. Add 20 kg of vinyl acetate and 5 kg of ethyl acrylate as component A, and add 10 kg of absolute ethanol as a diluent into the reaction kettle together, heat up and stir.

[0034] ②. 45 kg of vinyl acetate, 2.5 kg of ethyl acrylate, 2.5 kg of methyl acrylate, 4 kg of methyl methacrylate, 5 kg of acrylic acid, 10 kg of acrylamide, 6 kg of hydroxypropyl acrylate, azobisisobutyronitrile 0.9 kg is added to the drop-adding tank as component B. When the temperature of the material in the kettle rises to the reflux temperature, drop it into the kettle within 5 hours.

[0035] ③. Add 70 kg of 95% industrial alcohol and 20 kg of deionized water to the kettle after 2 hours of hea...

Embodiment 2

[0037] Embodiment 2 The preparation of alcohol water-soluble resin of the present invention

[0038] Weigh raw materials according to the following ratio:

[0039] A component: vinyl acetate 25 kg

[0040] Methyl acrylate 1 kg

[0041] Methyl methacrylate 7 kg

[0042] Add 15 kg of absolute ethanol as diluent

[0043] B component: vinyl acetate 35 kg

[0044] Methyl acrylate 2 kg

[0045] Methyl methacrylate 8 kg

[0046] Acrylic 3 kg

[0047] Hydroxypropyl Acrylate 15kg

[0048] Acrylamide 4 kg

[0049] Benzoyl Peroxide 0.6kg

[0050] Prepare 15 kilograms of deionized water and 75 kilograms of 95% denatured alcohol as diluents in addition, and the preparation method is the same as in Example 1 to obtain 200.7 kilograms of resin with a solid content of 50%.

[0051] The resin prepared by the formula described in Example 2 is most suitable for producing heat-resistant, retort-resistant intaglio plastic composite ink.

Embodiment 3

[0052] Embodiment 3 The preparation of alcohol water-soluble resin of the present invention

[0053] Weigh raw materials according to the following ratio:

[0054] A component: vinyl acetate 15 kg

[0055] Methyl acrylate 5 kg

[0056] Add 10 kg of absolute ethanol and 2 kg of deionized water as diluents

[0057] B component: vinyl acetate 50 kg

[0058] Methyl acrylate 10 kg

[0059] Acrylic 2 kg

[0060] Acrylamide 10 kg

[0061] Hydroxyethyl Acrylate 8 kg

[0062] Azobisisobutyronitrile 0.8 kg

[0063] In addition, 18 kilograms of deionized water and 70 kilograms of 95% technical alcohol were used as diluents, and the preparation method was the same as in Example 1 to obtain 200.7 kilograms of resin with a solid content of 50%.

[0064] The resin prepared by the formula described in Example 3 is suitable for producing common gravure plastic composite ink.

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PUM

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Abstract

The invention provides an alcohol water-soluble resin and a preparation method thereof. The alcohol water-soluble resin can be dissolved in the mixed solvent of alcohol and water and the polymerization raw materials of the alcohol water-soluble resin mainly consit of the vinyl acetate monomers, and simultaneously the methacrylate monomers, the acylid acids and other hydrophilic functional monomers are added into the raw materials so as to ensure that the performance of the resin can meet the requirements for particular use. The invention also provides an alcohol water-soluble ink, compound adhesive, antiseptic varnish for printing, gloss varnish for woodware, decorative coatings for plastic surface and hair colorants that are prepared by adotping resin and the preparation methods thereof.

Description

Technical field [0001] The benzene invention relates to an alcohol-water-soluble copolymer resin, specifically to an alcohol-water-soluble resin used as the main raw material for preparing alcohol-water-soluble fine chemical products such as alcohol-water-soluble inks, coatings, and plastic composite adhesives, and its preparation method. technical background [0002] Resin is the main raw material for the production of fine chemical products such as inks, adhesives, and coatings. Resin determines the performance, cost, and solvent dilution of these products; currently, most of the resins used to produce the above products are based on benzene, Diluted with ketone solvents, these solvents not only seriously pollute the environment, but also because they are petroleum refined products, with the rise of petroleum prices, the cost rises sharply; due to the pressure of cost and environmental protection, there are various systems in the market. Esters are resins used as solvents...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F218/08C09D11/10C09D131/04B05D7/06B05D7/02A61K31/765A61Q5/06C09J131/04C08F220/06C08F220/10C09D11/00
Inventor 邹明国钟文军邹文俊
Owner 常熟国和新材料有限公司
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