Method for determining coal ignitability

A measurement method and tendency technology, applied in the direction of fuel oil testing, material inspection products, etc., can solve the problem of long test cycle (often ten hours or even dozens of hours, can not reflect the oxidation and spontaneous combustion process in the low temperature oxidation stage, flammable and non-flammable). The problems of inconsistent classification standards of ash-based volatiles have achieved the effect of wide practicability, improved measurement accuracy and simple method.

Inactive Publication Date: 2011-05-11
CHINA UNIV OF MINING & TECH
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Problems solved by technology

The adiabatic oxidation method used abroad has a long test period (often more than ten hours or even dozens of hours), and the test conditions are harsh; ) under the condition of oxidative self-heating, which cannot reflect the whole oxidative self-ignition process including the low-temperature oxidation stage
The methods used in China have the following shortcomings: first, the physical adsorption of oxygen by coal is only related to the surface properties and pore structure of coal, and cannot reflect the comprehensive characteristics of coal spontaneous combustion low-temperature slow oxidation stage and accelerated oxidation; second, the coal at room temperature The amount of oxygen absorbed does not represent the amount of oxygen participating in the oxidation reaction. The amount of oxygen participating in the oxidation reaction mainly depends on the type and number of active groups in the coal structure; third, the classification standards are not uniform, and different combustible and ash-free volatile The classification standards are inconsistent, and the tendency test results will be seriously misjudged due to the fluctuation of the volatile content of the flammable ash-free base within the allowable error range of the critical value

Method used

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  • Method for determining coal ignitability
  • Method for determining coal ignitability
  • Method for determining coal ignitability

Examples

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Embodiment 1

[0019] Example 1: Take coal samples from Changcun Mine in Yima, Henan, and after crushing and screening, take coal samples with a particle diameter of 0.18 mm to 0.38 mm, place the coal samples at 40°C for air drying, and take 50 Put ±0.1g air into the coal sample tank from the dry coal sample, and evenly cover a layer of asbestos with a thickness of 2mm to 3mm above the coal sample. Put the coal sample tank into the test box, feed dry air (oxygen concentration 20.96%) into the coal sample tank at a relatively high and stable flow rate of 96ml / min, and set the temperature of the test box to run at a constant temperature of 40°C. When the temperature of the coal sample reaches 40°C, adjust the dry air flow into the coal sample tank to a lower flow rate of 8ml / min and keep it stable, and set the temperature of the test box to 0.8°C / min. ℃ on the basis of constant temperature operation, the temperature is increased by 0.8 ℃ per minute, and the data collector is turned on at the s...

Embodiment 2

[0025] Embodiment two, take the coal sample of Gequan Mine in Xingtai, Hebei, steps and conditions are the same as embodiment one, omitted. The measured oxygen concentration C was 20.29%. The intersection temperature T is 182.7°C, and the oxygen concentration parameter C and the intersection temperature T are substituted into the calculation formula to obtain the coal spontaneous combustion tendency judgment index I value,

[0026] I=929, 600≤929≤1200, it is determined that the coal in Gequan Mine in Xingtai, Hebei Province is a spontaneous combustion coal seam.

Embodiment 3

[0027] Embodiment three, take the coal sample of Kabuliang mining area, Shizuishan, Ningxia, the steps and conditions are the same as in embodiment one, omitted. The measured oxygen concentration C was 20.72%. The temperature index T of the intersection point is 207.1°C, and the oxygen concentration parameter C and the temperature T of the intersection point are substituted into the calculation formula to obtain the coal spontaneous combustion tendency judgment index I value,

[0028] I=1275>1200, it is determined that the coal in the Kabuliang mining area of ​​Shizuishan, Ningxia is a coal seam that is not prone to spontaneous combustion.

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Abstract

A measuring method of coal self combustion tendency is suitable for the qualitative analysis and classification of the self combustion tendency of coal bed in a coal mine. The method includes the following steps: through testing the oxygen concentration at the air outlet of a coal sample tank when coal sample reaches the set temperature, the oxidation rate of coal at a low-temperature oxidation stage is judged; through testing cross-point temperature, the oxidation rate at an accelerated oxidation stage is judged; then, combined calculation is carried out through adopting the two parameters to obtain the value of coal self combustion tendency determination index; moreover, the smaller the value is, the easier the self combustion becomes and vice versa. Therefore, the method effectively solves the problem of comprehensive reflection of the characteristics of low-temperature slow oxidation stage and accelerated oxidation stage of coal self combustion, and increases the measuring accuracy of coal self combustion tendency; moreover, with simple and reliable operation and unified classification standard, the entire measuring process only needs to test two parameters and can be completed within 3 hours to 4 hours. In addition, with a simple method, convenient operation, time saving and labor saving and accurate testing result, the invention has wide practicality in the related field.

Description

technical field [0001] The invention relates to a method for measuring the spontaneous combustion tendency of coal, which is suitable for the qualitative and classification of the spontaneous combustion tendency of coal seams in coal mines. Background technique [0002] Coal spontaneous combustion is one of the major disasters faced by coal mine safety production in my country. Coal seams prone to spontaneous combustion account for 79.93% of the total number of mined coal seams in China, and mines with thick coal seams in key state-owned coal mines basically have the problem of spontaneous combustion. The determination of coal spontaneous combustion tendency is the prerequisite for effective fire prevention and extinguishing work in mines. At present, the methods for measuring coal spontaneous combustion tendency: foreign countries mainly include adiabatic oxidation method (USA, Australia, etc.), high temperature activation energy method (Poland), intersection temperature me...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N33/22
Inventor 王德明仲晓星戚绪尧周福宝李增华
Owner CHINA UNIV OF MINING & TECH
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