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Method for ion plating wear resistant anti-electric corrosion alloy on pure copper surface

An ion plating and anti-corrosion technology, applied in ion implantation plating, sputtering plating, vacuum evaporation plating, etc., can solve the problem of high production cost of arc melting method, reduction of contact current breaking capacity, uniformity of material structure Low-level problems, to achieve good anti-welding performance, good activation effect, high affinity effect

Inactive Publication Date: 2010-06-02
HENAN POLYTECHNIC UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the Cu-Cr series alloys prepared by these methods have been used as contact materials, they all have their own shortcomings and deficiencies.
Among them, the main disadvantage of powder metallurgy method is that the size and spacing between Cr particles are too large, the structure uniformity of the material is low, and the content of oxygen and nitrogen is too high, which reduces the breaking capacity of the contact current.
The disadvantage of the infiltration method is that the production efficiency is low, the chromium particles are relatively coarse, and the chromium content must reach a considerable proportion, which seriously reduces the conductivity
However, the production cost of the arc melting method is relatively high, and many process parameters need to be further explored and improved.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A pure copper plate with a thickness of 2mm, with a length and width of 10mm×20mm, is ion-plated on its surface with a layer of wear-resistant and anti-corrosion alloy. The process steps are:

[0025] The first step is to polish and degrease the pure copper surface and install it in the furnace;

[0026] The second step, vacuumize to about 5×10 -2 Pa, pass argon gas to 20Pa, connect the DC power supply, apply a 350V negative bias voltage between the pure copper parts and the vacuum chamber shell, and purify and activate the pure copper surface through glow ion bombardment to remove pure copper Surface oil film, oxide film, time 8min;

[0027] The third step is to turn on the arc power supply, arc discharge is generated between the arc hook and the alloy target Cu-Cr (20%wt), the single target operating current is 35A, and the time is 180min, the target particles evaporated by the magnetron arc are deposited On the surface of pure copper, a uniform coating layer is for...

Embodiment 2

[0030] A pure copper plate with a thickness of 5mm, with a length and width of 12mm×25mm, is ion-plated on its surface with a layer of wear-resistant and anti-corrosion alloy. The process steps are the same as above, and the specific parameters are:

[0031] Polish the surface of pure copper, degrease it and load it into the furnace; vacuumize to about 10 -1 Pa, pass argon gas to 25Pa; connect the DC power supply, apply a 400V negative bias voltage between the pure copper parts and the vacuum chamber shell, purify and activate the pure copper surface through glow ion bombardment, and remove the pure copper Oil film and oxide film on the surface, the time is 6min; then the arc power supply is turned on, arc discharge is generated between the arc hook and the alloy target Cu-Cr (25%wt), the single target working current is 40A, the time is 120min, and the magnetron arc Evaporated target particles are deposited on the surface of pure copper to form a uniformly plated Cu-Cr alloy ...

Embodiment 3

[0033] A pure copper plate with a thickness of 8mm, with a length and width of 15mm×30mm, is ion-plated on its surface with a layer of wear-resistant and anti-corrosion alloy. The process steps are the same as above, and the specific parameters are:

[0034] Polish the surface of pure copper and degrease it before loading into the furnace; evacuate to about 1Pa, pass argon gas to 25Pa, connect the DC power supply, apply a 450V negative bias voltage between the pure copper parts and the vacuum chamber shell, and pass the glow Purify and activate the surface of pure copper by photoion bombardment, remove the oil film and oxide film on the surface of pure copper for 5 minutes; Arc discharge is generated, the working current of a single target is 55A, and the time is 60min. A uniformly plated Cu-Cr alloy layer is formed on the surface of pure copper, and its composition is consistent with that of the target material; Cool down and polish after coming out of the furnace.

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Abstract

The invention provides a method for plating an abrasion-resistant electrical-erosion-resistant alloy on pure copper surface ions, which comprises the following steps: after the surface of pure copperis polished, deoiled and dried in the air, the pure copper is put into a furnace which is then vacuumized, pumped in argon gas and connected with a DC power source; negative bias is imposed between pure copper pieces and a shell of a vacuum chamber and pretreatment is conducted to the surface of the pure copper by glow ion bombardment; an oil film and an oxide film on the surface are removed; an arc power source is switched on, arc discharge is generated between an arc generating hook and a Cu-Cr alloy target; target particles vaporized by a magnetic control arc is deposited on the surface ofthe pure copper to form a uniformly-coated alloy layer; the arc power source and the DC power source are disconnected, cooling is conducted under the protection of argon gas, and the pure copper is taken out and then polished. By adopting the method of the invention, an alloy layer with good abrasion-resistance and electrical-erosion resistance can be obtained on the surface of the pure copper, while the core part of the pure copper keeps excellent electric conductivity of pure copper and the surface part displays fully the characteristics of high current breaking capacity, high voltage bearing capacity, good fusing soldering resistance, low arc burning loss, low loss of contact-wear and the like of the Cu-Cr alloy.

Description

Technical field: [0001] The invention belongs to the technical field of metal material surface modification, and in particular relates to a method for ion-plating a wear-resistant and anti-corrosion alloy on the surface of pure copper. Background technique: [0002] Pure copper has excellent electrical and thermal conductivity, and is widely used in conductive components, heat transfer elements of heat exchangers and other components. However, in some applications, especially those requiring wear and corrosion resistance, pure copper obviously shows its own shortcomings. [0003] Take the electrical contacts of conductive components as an example. The electrical contact is the key component of the vacuum circuit breaker. The ideal electrical contact material should have the following properties: ① High current breaking capacity; ② High voltage withstand capacity; ③ High electrical conductivity and thermal conductivity; ④ Anti-welding performance Good; ⑤ low arc burn rate; ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C14/35C23C14/02C23C14/54C23C14/16
Inventor 袁庆龙侯文义
Owner HENAN POLYTECHNIC UNIV