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Method for ion plating wear resistant anti-electric corrosion alloy on pure copper surface

An ion plating and anti-corrosion technology, applied in ion implantation plating, sputtering plating, vacuum evaporation plating, etc., can solve the problem of high production cost of arc melting method, reduction of contact current breaking capacity, uniformity of material structure Low-level problems, to achieve good anti-welding performance, good activation effect, high affinity effect

Inactive Publication Date: 2009-01-28
HENAN POLYTECHNIC UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the Cu-Cr series alloys prepared by these methods have been used as contact materials, they all have their own shortcomings and deficiencies.
Among them, the main disadvantage of powder metallurgy method is that the size and spacing between Cr particles are too large, the structure uniformity of the material is low, and the content of oxygen and nitrogen is too high, which reduces the breaking capacity of the contact current.
The disadvantage of the infiltration method is that the production efficiency is low, the chromium particles are relatively coarse, and the chromium content must reach a considerable proportion, which seriously reduces the conductivity
However, the production cost of the arc melting method is relatively high, and many process parameters need to be further explored and improved.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A pure copper sheet with a thickness of 2mm, a length and a width of 10mm×20mm, ion plating a layer of wear-resistant and anti-corrosion alloy on its surface, the process steps are:

[0025] The first step is to polish and degrease the surface of the pure copper and install it into the furnace;

[0026] The second step, vacuum to about 5×10 -2 Pa, blow argon to 20Pa, switch on the DC power supply, apply a negative bias voltage of 350V between the pure copper part and the vacuum chamber shell, purify and activate the surface of the pure copper by glow ion bombardment to remove the pure copper Oil film and oxide film on the surface, time 8min;

[0027] The third step, turn on the arc power supply, arc discharge is generated between the arc hook and the alloy target Cu-Cr (20%wt), the single target working current is 35A, the time is 180min, and the target particles evaporated by the magnetron arc are deposited On the surface of pure copper, a uniform plating layer is formed, ...

Embodiment 2

[0030] A pure copper sheet with a thickness of 5mm with a length and width of 12mm×25mm. The surface is ion-plated with a layer of wear-resistant and anti-corrosion alloy. The process steps are the same as the above. The specific parameters are:

[0031] After polishing the surface of pure copper and degreasing treatment, install it into the furnace; vacuumize to about 10 -1 Pa, argon gas to 25Pa; turn on the DC power supply, apply 400V negative bias between the pure copper part and the vacuum chamber shell, purify and activate the pure copper surface by glow ion bombardment to remove the pure copper Oil film and oxide film on the surface, time 6min; then turn on the arc power supply, arc discharge occurs between the arc hook and alloy target Cu-Cr (25%wt), single target working current is 40A, time 120min, magnetron arc The evaporated target particles are deposited on the surface of pure copper to form a uniformly plated Cu-Cr alloy layer whose composition is the same as that of ...

Embodiment 3

[0033] A pure copper sheet with a thickness of 8mm, the length and width dimensions are 15mm×30mm, and a layer of wear-resistant and anti-corrosion alloy is ion-plated on its surface. The process steps are the same as above. The specific parameters are:

[0034] After polishing and degreasing the surface of the pure copper, install the furnace; vacuumize to about 1Pa, ventilate argon to 25Pa, switch on the DC power supply, apply a negative bias of 450V between the pure copper part and the vacuum chamber shell, and pass the vacuum Photoion bombardment is used to purify and activate the surface of pure copper, remove the oil film and oxide film on the surface of pure copper, for 5 minutes; then turn on the arc power supply, and the arc hook and the alloy target Cu-Cr (30%wt) are between Generate arc discharge, single target working current is 55A, time 60min, a uniformly plated Cu-Cr alloy layer is formed on the surface of pure copper, its composition is consistent with the target m...

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Abstract

The invention provides a method for plating an abrasion-resistant electrical-erosion-resistant alloy on pure copper surface ions, which comprises the following steps: after the surface of pure copper is polished, deoiled and dried in the air, the pure copper is put into a furnace which is then vacuumized, pumped in argon gas and connected with a DC power source; negative bias is imposed between pure copper pieces and a shell of a vacuum chamber and pretreatment is conducted to the surface of the pure copper by glow ion bombardment; an oil film and an oxide film on the surface are removed; an arc power source is switched on, arc discharge is generated between an arc generating hook and a Cu-Cr alloy target; target particles vaporized by a magnetic control arc is deposited on the surface of the pure copper to form a uniformly-coated alloy layer; the arc power source and the DC power source are disconnected, cooling is conducted under the protection of argon gas, and the pure copper is taken out and then polished. By adopting the method of the invention, an alloy layer with good abrasion-resistance and electrical-erosion resistance can be obtained on the surface of the pure copper, while the core part of the pure copper keeps excellent electric conductivity of pure copper and the surface part displays fully the characteristics of high current breaking capacity, high voltage bearing capacity, good fusing soldering resistance, low arc burning loss, low loss of contact-wear and the like of the Cu-Cr alloy.

Description

Technical field: [0001] The invention belongs to the technical field of surface modification of metal materials, and specifically relates to a method for ion plating a wear-resistant and electro-corrosive alloy on the surface of pure copper. Background technique: [0002] Pure copper has excellent electrical and thermal conductivity, and is widely used in conductive components, heat exchangers and heat transfer components. However, in some applications, especially those requiring wear resistance and electrical corrosion resistance, pure copper clearly shows its own shortcomings. [0003] Take the electrical contacts of conductive components as an example. Electrical contacts are the key components of vacuum circuit breakers. The ideal electrical contact material should have the following properties: ①High current breaking capacity; ②High voltage withstand ability; ③High electrical conductivity and thermal conductivity; ④Anti-welding performance Good; ⑤ low arc burning rate; ⑥ low...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C14/35C23C14/02C23C14/54C23C14/16
Inventor 袁庆龙侯文义
Owner HENAN POLYTECHNIC UNIV