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Environment-friendly imitation gold plating production technology

A production process and environment-friendly technology, which is applied in the field of environment-friendly multi-complex copper-zinc-tin alloy imitation gold electroplating processing technology, can solve the problem of narrow controllable process range of coating color, incomparable cyanide imitation gold electroplating, product batch The secondary color is not uniform and other problems, to achieve the effect of bright color, high practical value, and realistic appearance

Inactive Publication Date: 2010-03-10
SHENYANG NORMAL UNIV
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Problems solved by technology

At present, domestic research on cyanide-free imitation gold electroplating is mainly concentrated in the stage of laboratory condition exploration. Due to the instability of the plating solution, it is difficult to realize industrialization. At the same time, the controllable process range of the coating color is narrow, resulting in the variation of product batch color. Not uniform, which is the key to its incomparability to cyanide imitation gold plating, so its process has not been widely used

Method used

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  • Environment-friendly imitation gold plating production technology
  • Environment-friendly imitation gold plating production technology
  • Environment-friendly imitation gold plating production technology

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Embodiment 1

[0017] Through experiment optimization, the present invention proposes a new gold-imitating electroplating process of environment-friendly multi-complex copper-zinc-tin alloy. Cu 2+ , Zn 2+ for d 10 Electronic configuration, the electrochemical reaction overvoltage of hydrated complex ions is very small. When only one ligand is used, the overvoltage of the plating solution is either too low or too high, and it is difficult to meet the requirements even if the concentration and pH of the complexing agent are changed. In order to improve the overvoltage of the reaction, the present invention introduces potassium sodium tartrate and glycerin with hydroxyl structure as auxiliary ligands as additives in the pyrophosphate system, and its hydroxyl group can participate in coordination to change the complex ion structure and electrode surface state. Finally, the purpose of co-deposition is achieved. In addition, the polyhydroxy group has a chelate structure, which can be used as a ...

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Abstract

Environment-friendly imitation gold plating production technology aims at solving the technical problems that the stability of plating solution is poor and the range of controllable color parameters is narrow in the present imitation gold plating technology. Potassium pyrophosphate is used as a main complexing agent, and copper sulfate and zinc sulfate are used as main salt, while nitrilotriaceticacid and seignette salt are used as auxiliary complexing agent for performing Cu-Zn-Sn ternary non-cyanide imitation gold plating. Imitation gold coating similar to real gold can be obtained in the technology. Experiments show that, compared with the previous imitation gold plating technology, the novel imitation gold plating technology is easier to control, the stability is greatly improved, theconcentration of main salt is lower, the technology is simpler and cyanide is not used as the complexing agent anymore. Therefore, compared with the conventional technology, toxicity and pollution ofthe novel technology are reduced significantly, thus benefiting popularization of green production.

Description

technical field [0001] The invention relates to an environment-friendly multi-complex copper-zinc-tin alloy imitation gold electroplating process, which is a means for the surface decoration plating process of metal or non-metal materials. Background technique [0002] The research of environment-friendly imitation gold electroplating process has become a research hotspot at home and abroad because of its huge processing market and the country's increasing environmental protection control. [0003] At present, the cyanide-free imitation gold electroplating process proposed to be applied to production at home and abroad includes binary (Cu-Zn, Cu-Sn) alloys, ternary (Cu-Zn-Sn, Cu-Sn-In) alloys and quaternary (Cu-Zn-Sn) alloys. - Zn-Sn-In, Cu-Sn-In-Ni) alloys. Systems include pyrophosphate, citrate, tartrate, HEDP systems, etc. According to current data records, to obtain a bright imitation gold coating must add appropriate additives, such as some alcohol amines or sulfamic ...

Claims

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Application Information

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IPC IPC(8): C25D3/58
Inventor 李华为
Owner SHENYANG NORMAL UNIV
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