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Catalytic reactor

A reactor and reaction module technology, applied in chemical/physical/physical-chemical stationary reactors, chemical instruments and methods, chemical/physical processes, etc., can solve the catalyst structure and plate heat transfer obstacles, difficult to remove or replace the catalyst Structure, small size, etc.

Active Publication Date: 2014-06-04
COMPACTGTL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, where there is a large pressure differential between the two fluids, this will tend to bend the plate, allowing syngas to bypass the catalyst structure, and heat transfer between the catalyst structure and the plate is hindered and may be difficult. Remove or replace the catalyst structure; but if the plates are strong enough to resist the pressure differential, then the plates will have to be thicker and / or the channels narrower, and the total catalyst-laden channel volume as a proportion of the total reactor volume will tend to smaller

Method used

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Embodiment Construction

[0019] The present invention relates to chemical processes for converting natural gas (mainly methane) into longer chain hydrocarbons. The first stage of the process is the production of syngas, preferably involving steam reforming, i.e. the reaction:

[0020] H 2 O+CH 4 →CO+3H 2

[0021] The reaction is endothermic and can be catalyzed by the rhodium or platinum / rhodium catalyst in the first gas flow channel. The heat required to cause this reaction can be provided by burning a fuel gas, such as methane or another short chain hydrocarbon (eg, ethane, propane, butane), carbon monoxide, hydrogen, or a mixture of these gases, which is exothermic, And can be catalyzed by a palladium / platinum catalyst in an adjacent second gas flow channel. Alternatively, syngas can be produced by partial oxidation processes or autothermal processes, which are well known processes; these processes produce syngas with slightly different compositions.

[0022] A Fischer-Tropsch synthesis is th...

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Abstract

A reactor module for Fischer-Tropsch synthesis having a generally rectangular reactor block with a stack of plates defining flow channels for coolant and flow channels for the synthesis reaction arranged alternately in the block. The synthesis flow channels extend in a generally vertical direction between upper and lower faces of the reactor block and are defined by plates in combination with either bars or sheets such that each channel is of width no more than 200 mm. The coolant flow channels are oriented in the same direction, and communicate through distributor chambers with inlet and outlet ports at side faces of the reactor block. A plant may contain a multiplicity of such reactor modules operating in parallel, the modules being interchangeable and replaceable. The temperature control is enhanced by allowing the coolant flow to be parallel to the synthesis gas flow.

Description

technical field [0001] The present invention relates to a catalytic reactor suitable for the conversion of natural gas into longer chain hydrocarbons, in particular for carrying out chemical processes of Fischer-Tropsch synthesis, and to the inclusion of such a catalytic reactor to The equipment that performs the process. Background technique [0002] A process is described in WO01 / 51194 and WO03 / 048034 (Accentus plc) in which methane is reacted with steam to generate carbon monoxide and hydrogen in a first catalytic reactor; the resulting gas mixture is then used in a second catalytic reactor Perform a Fischer-Tropsch synthesis. The overall result is the conversion of methane to higher molecular weight hydrocarbons that are typically liquid at ambient conditions. The two stages of the process, steam / methane reforming and Fischer-Tropsch synthesis, require different catalysts and heat transfer to or from the reaction gas, respectively, because the reactions are endothermic...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J19/24C10G2/00
CPCB01J2219/2486B01J2219/2498B01J2219/2462C10G2/341B01J2219/2485B01J2219/2479B01J2219/245B01J2219/2453B01J2219/00074B01J2219/2497B01J2219/185B01J2219/2458C10G2/34B01J2219/0002B01J19/249B01J2219/2459
Inventor M·J·鲍C·D·李-塔夫内尔
Owner COMPACTGTL