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Environmentally friendly lead-containing solder capable of suppressing lead from volatilizing at high temperature

An environmentally friendly, high-temperature technology, applied in the direction of manufacturing tools, welding/cutting media/materials, welding media, etc., to achieve the effect of safe and convenient use, good environmental conditions, and no impact on health

Inactive Publication Date: 2013-11-13
CHONGQING UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This covering agent is mainly used for lead bath quenching of steel wire, not suitable for electronic brazing

Method used

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  • Environmentally friendly lead-containing solder capable of suppressing lead from volatilizing at high temperature
  • Environmentally friendly lead-containing solder capable of suppressing lead from volatilizing at high temperature

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Example 1: Put 630g of Sn and 370g of Pb in an open electric furnace for oxidation refining and boiling refining, then pour into a closed converter, add 0.5g of Al, 0.01g of Ni, and 0.005g of Ga for modification and refining, and the obtained The solder is heated to 800°C at a rate of 10°C per minute under a protective atmosphere, and it is measured that the volatilization of lead is 65% lower than that of Sn-37Pb.

Embodiment 2

[0025] Example 2: Put 620g of Sn, 360g of Pb, and 20g of Ag in an open electric furnace for oxidation refining and boiling refining, then inject into a closed converter, add 0.1g of Al, 1.5g of Bi, and 0.05g of In to improve The resulting solder is heated to 800°C at 10°C per minute under a protective atmosphere, and the measured lead volatilization is 72% lower than that of Sn-37Pb.

Embodiment 3

[0026] Example 3: Put 550g of Sn, 430g of Pb, and 20g of Sb in an open electric furnace for oxidation refining and boiling refining, then inject into a closed converter, add Ni 0.5g, P 0.05g, and Ti 0.005g to improve The resulting solder is heated to 800°C at 10°C per minute under a protective atmosphere, and it is difficult to detect the volatilization of lead.

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Abstract

The invention provides an environmentally friendly lead-containing solder capable of suppressing lead from volatilizing at high temperature, which is used in the electronic industry. The lead-containing solder comprises the following components: 0-4.0 percent by weight of Ag, 0-3.0 percent by weight of Sb, one or more of Ni, Al, Bi, Ca, In, P and Ti and the balance of Sn and Pb, wherein the quantity of each of the Ni, the Al, the Bi, the Ca, the In, the P and the Ti is 0.0001-0.2 percent by weight; the total quantity of the elements of the Ni, the Al, the Bi, the Ga, the In, the P, the Ti, and the like does not exceed 0.3 percent by weight at most; and the elements can form various better combinations, such as the combination of Ni and P, the combination of Ni, P and Ti and the combination of Ni, P and Ga, or only the elements of the Ni, the Al, and the like are selected. In the invention, after the solder is molten, a surface modification film can be automatically generated and can obviously suppress the volatilization of the lead at high temperature, and the solder has good environment condition in a using process, has no influence on the health of operators, is safe and convenient to use and has low cost, thus the solder is a new-generation micro-connection material used for environmentally friendly manufacturing an electronic product.

Description

[0001] The present invention is a divisional application of the invention patent application with application number 200810069745.8. technical field [0002] The invention relates to a lead-containing solder used in the electronics industry to inhibit lead from volatilizing and polluting the environment at high temperatures. Background technique [0003] For a long time, lead-containing solder has been widely used as electronic soldering material due to its low cost and excellent performance. Since lead pollutes the environment, the world has started research on lead-free electronic solder since the 1990s, but up to now, a kind of lead-free solder with comprehensive performance comparable to that of Sn-Pb solder has not been found, and there is no Find a comprehensive solution to replace Pb. In many electronic devices, it is difficult to truly realize lead-free because the reliability of lead-free solder cannot be guaranteed. Therefore, in the future, electronic solder wil...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B23K35/26
Inventor 杜长华黄伟九朱新才许惠斌陈方
Owner CHONGQING UNIV OF TECH