A kind of silica sand colorant, colored silica sand and preparation method of colored silica sand
A colorant and silica sand technology, applied in the field of preparation of colored silica sand, can solve the problems of poor long-term color stability, difficulty in coloring silica sand, etc.
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[0020] The present invention also provides a method for preparing colored silica sand, wherein the method comprises:
[0021] Mix the silica sand with the resin evenly at 100-200°C, and then make the mixture of the silica sand and the resin contact with the silica sand colorant and curing agent of the present invention to form a colored resin layer on the surface of the silica sand.
[0022] In a preferred situation, the silica sand before being mixed with the resin can be heat-treated at 250-1000°C for 1-60min, more preferably at 400-800°C for 15-30min. After the silica sand is heat-treated at the above temperature, the silica sand can be The impurities on the surface are fully removed, which can promote the close combination of silica sand and colored resin layer. In a further preferred situation, transfer the heat-treated silica sand to a sand mixer, and naturally cool it to 100-200°C under stirring at a stirring speed of 50-200r / min, add resin, and continue stirring until ...
Embodiment 1
[0031] This example is used to illustrate the silica sand colorant, colored silica sand and the preparation method of colored silica sand of the present invention.
[0032] Preparation of silica sand colorant:
[0033] 14g of iron yellow powder (320 mesh sieve residue≤0.5% by weight) purchased from Shanghai Xinyan Pigment Co., Ltd. and 86g of titanium dioxide (325 mesh sieve residue≤0.05% by weight) purchased from Langfang Xiangyu Titanium Dioxide Manufacturing Co., Ltd. Mix well to obtain 100 g of the silica sand colorant (C1) of the present invention.
[0034] Preparation of colored silica sand:
[0035] (1) Silica sand surface pretreatment step: Add 100kg of silica sand into the muffle furnace, roast at 800°C for 20 minutes, then directly transfer the roasted silica sand to the sand mixer, and cool it at a stirring speed of 100r / min. When the temperature reaches 150°C, add 5kg of epoxy resin binder (E51, epoxy value 0.48-0.54eq / 100g), and continue stirring.
[0036] (2) ...
Embodiment 2
[0038] This example is used to illustrate the silica sand colorant, colored silica sand and the preparation method of colored silica sand of the present invention.
[0039] Preparation of silica sand colorant:
[0040] The silica sand colorant (C2) was prepared according to the method of Example 1, except that the composition of the silica sand colorant was shown in Table 1.
[0041] Preparation of colored silica sand:
[0042] (1) Silica sand surface pretreatment step: Add 100kg of silica sand into the muffle furnace, roast at 1000°C for 1min, then directly transfer the roasted silica sand to the sand mixer, and cool it at a stirring speed of 200r / min When the temperature reaches 200°C, add 10kg of epoxy resin adhesive (model is E51, epoxy value is 0.48-0.54eq / 100g), and continue stirring.
[0043] (2) Silica sand coloring step: at a temperature of 200°C, add 0.01kg of silica sand colorant C2 to the silica sand in step (1), after stirring for 10s, add 5kg of resole phenolic...
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