A kind of preparation method of plastic product and a kind of plastic product

A technology of plastic products and plastics, which is applied in the direction of superimposed layer plating, metal material coating process, liquid chemical plating, etc. Advanced problems, to achieve the effect of low cost, low energy requirement and simple process

Inactive Publication Date: 2011-12-28
BYD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The invention aims to solve the technical problems in the prior art that the plastic surface metallization process is complicated, the energy requirement is high, and the adhesion between the coating and the plastic substrate is poor

Method used

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Examples

Experimental program
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Effect test

preparation example Construction

[0015] The invention provides a kind of preparation method of plastic product, comprises the following steps:

[0016] 1) molding plastic substrate; the plastic substrate is a thermoplastic or thermosetting plastic containing an electroless plating accelerator, and the electroless plating accelerator is evenly distributed in the thermoplastic or thermosetting plastic; the electroless plating accelerator has the general formula ABO 3 A perovskite structure compound, wherein A contains at least one of the elements in the 9th, 10th, and 11th columns of the periodic table, and A selectively contains one or more of the IA, IIA group elements, and lanthanide elements; B One or more of the group IVB and VB elements;

[0017] 2) Laser vaporizes the surface of the plastic substrate, exposing the electroless plating accelerator;

[0018] 3) Electroless copper plating or electroless nickel plating on the surface of the electroless plating promoter in step 2), continue to perform at leas...

Embodiment 1

[0050] (1) CaCu 3 Ti 4 o 12 Put it into a high-speed ball mill and mill it for 10 hours until the average particle size of the powder is 700nm; mix PPE / PPS resin alloy, CaCu 3 Ti 4 o 12 , calcium silicate fiber and antioxidant 1010, according to the mass ratio of 100:10:30:0.2, mixed with a high mixer, extruded and pelletized with a twin-screw extruder (Nanjing Rubber and Plastic Machinery Factory), and injection molded into LED Lamp circuit board carrier.

[0051] (2) Use an infrared laser (Tide, DPF-M12) to print the metal circuit pattern on the LED lamp circuit board carrier. The laser parameters are: wavelength 1064nm, scanning speed 1000mm / s, step size 9μm, delay 30μs, frequency 40KHz , power 3W, filling pitch 50 μm; after the laser irradiation is completed, the surface of the plastic carrier is ultrasonically cleaned.

[0052] (3) Immerse in the chemical nickel plating solution for 10 minutes to form a nickel layer with a thickness of 3 μm; immerse in the chemical ...

Embodiment 2

[0055] Adopt the method identical with embodiment 1 to prepare the plastic product of the present embodiment, difference is:

[0056] In step (1), the CuNiTi 2 o 6 Ball milled to an average particle size of 800nm ​​and dried; PEEK resin, CuNiTi 2 o 6 , glass fiber and antioxidant 168 are mixed according to the mass ratio of 100:20:30:0.2, extruded and granulated, and then injection molded to form an automobile engine electronic connector housing;

[0057] In step (3), the order of electroless plating is: first electroless nickel plating forms 2 μm thick nickel layer in 8 minutes, then electroless copper plating forms 13 μm thick copper layer in 3 hours, then electroless nickel plating forms 3 μm thick nickel layer in 10 minutes, Finally, a gold layer with a thickness of 0.03 μm is flash-plated.

[0058] Through the above steps, the plastic product used as the housing of the electronic connector of the automobile engine in this embodiment is obtained.

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Abstract

The invention discloses a preparation method of a plastic product. The method comprises: 1) forming a plastic matrix; the plastic matrix contains an electroless plating accelerator; the electroless plating accelerator is a perovskite structure compound with the general formula ABO3, wherein A contains At least one of the elements in the 9th, 10th, and 11th columns of the periodic table, A selectively contains one or more of the IA, IIA group elements, and lanthanide elements; B is one of the IVB, VB group elements. 2) The surface of the plastic substrate is vaporized by laser to expose the electroless plating accelerator; 3) The electroless copper or electroless nickel plating is performed, and at least one electroless plating and / or electroplating is continued to form a metal layer on the surface of the plastic substrate. The preparation method provided by the invention has the advantages of simple process, low energy requirement and low cost; in addition, the electroless plating accelerator is distributed in the plastic substrate, so the bonding force between the plating layer formed after electroless plating and the plastic substrate is very high. The present invention further discloses the plastic product prepared by the above method.

Description

[0001] This application is a divisional application with the applicant being BYD Co., Ltd., the filing date is January 15, 2010, the application number is 201010044447.0, and the invention title is "a preparation method of a plastic product and a plastic product". technical field [0002] The invention belongs to the field of surface metallization of non-metallic materials, and in particular relates to a preparation method of a plastic product and a plastic product. Background technique [0003] A metal layer is formed on the surface of the plastic, which is used as a channel for electromagnetic signal transmission, and is widely used in automobiles, industries, computers, communications and other fields. The selective formation of a metal layer on the plastic surface is a core link in the manufacture of such plastic products. There are many methods for plastic surface metallization production lines. In the prior art, metal nuclei are first formed on the surface of the plast...

Claims

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Application Information

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IPC IPC(8): C23C28/00C23C18/38C23C18/32B29C59/16
Inventor宫清周良苗伟峰张雄
OwnerBYD CO LTD