Titanium dioxide-soy protein isolate composite nano antimicrobial film and preparation method thereof
A technology of soybean protein isolate and titanium dioxide, which is applied in flexible covering, packaging, wrapping paper, etc., can solve the problems of environmental pollution, not easy to decompose and rot, and achieve the effect of broad antibacterial spectrum, delaying oxidative deterioration and good immediate effect.
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[0032] (1) Preparation of protein liquid: Glycerin (plasticizer), water, and soybean protein isolate are gradually added in the state of magnetic stirring to make protein liquid.
[0033] (2) Adjust the pH value: Use 0.1mol / L NaOH solution to adjust the pH value to 9-11.
[0034] (3) Constant temperature water bath heating: the water bath is controlled at 70°C-80°C, and heated for 20-30min. Turn on the magnetic stirrer to stir the solution in the water bath to make it heated evenly.
[0035] (4) Cooling: After heating in a water bath, cool to room temperature.
[0036] (5) Adding titanium dioxide: Measure a certain volume of the pre-dispersed titanium dioxide solution and add it to the cooled protein solution, so that the content of nano-titanium dioxide is 0.5-3.0g / 150ml film-forming solution, and magnetically stir for 1-2 hours.
[0037] (6) Filtration and degassing: quickly filter with four layers of gauze, and let it stand for half an hour to remove air bubbles.
[0038...
Embodiment 1
[0046]Soy protein isolate is 6g, glycerin 1.5g, titanium dioxide 0.5g, water 127mL.
[0047] The protein used should be soybean protein isolate, the quality meets the national standard, and it is fresh and not expired.
[0048] (1) Preparation of protein solution: Glycerin 1.5g, water 127mL, 6g soybean protein isolate was gradually added under the state of magnetic stirring (1200r / min) to prepare a solution with a certain concentration.
[0049] (2) Adjust the pH value: Use 0.1mol / L NaOH solution to adjust the pH value to about 10.00.
[0050] (3) Constant temperature water bath heating: the water bath is stably controlled at about 70°C, and heated for 20 minutes. Turn on the magnetic stirrer to stir the solution in the water bath to make it heated evenly.
[0051] (4) Cooling: After heating in a water bath, cool to room temperature.
[0052] (5) Adding titanium dioxide: Measure 16.7 mL of the pre-dispersed titanium dioxide solution (3%) into the cooled protein solution, an...
Embodiment 2
[0057] Soy protein isolate is 6g, glycerin 6.0g, titanium dioxide 1.5g, water 88mL.
[0058] (1) Preparation of protein solution: Glycerin 6.0g, water 88mL, under the state of magnetic stirring (1200r / min), 6g soybean protein isolate was gradually added to prepare a solution with a certain concentration.
[0059] (2) Adjust the pH value: Use 0.1mol / L NaOH solution to adjust the pH value to about 10.00.
[0060] (3) Constant temperature water bath heating: the water bath is stably controlled at about 70°C, and heated for 20 minutes. Turn on the magnetic stirrer to stir the solution in the water bath to make it heated evenly.
[0061] (4) Cooling: After heating in a water bath, cool to room temperature.
[0062] (5) Adding titanium dioxide: Measure 50 mL of the previously dispersed titanium dioxide solution (3%) into the cooled protein solution, and stir magnetically for 1.5 hours.
[0063] (6) Filtration and degassing: quickly filter the protein solution of the composite mem...
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