Coking coal modifier

A technology of modifier and coking coal, which is applied in the field of coking coal modifier and coking coal additive, which can solve the problems of complex treatment process, poor bonding performance, complex process, etc., and achieve the effect of reducing thermal reaction, improving strength and good coking effect

Inactive Publication Date: 2012-07-04
曹金贵
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For the defects of poor caking performance in weak caking coking coal, although corresponding technological measures (such as tamping coking, coal blending, coal humidity control, coke oven large-scale, CDQ, etc.) can be improved coke quality), but its process is complex, costly and limited in effect
[0003] At present, in order to improve the quality of coke in coking coal, additives are often used in the coking process. The additives used are generally some caking substances (such as pitch, tar, residual oil, pulp waste liquid, etc.), the principle is Use the caking property of additives during coking to improve the quality of coking coal, so as to achieve the purpose of improving the quality of coke, but the addition ratio is relatively high (generally as high as 1% or more), the treatment process is more complicated, and the cost is higher

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] The purity of boric acid as raw material is >98%; the purity of antimony oxide is 90-99%; the fixed carbon content in medium-temperature modified asphalt is 45-50%.

[0030] The mixing preparation method of the coking coal upgrading agent of the present invention is as follows: weighing various raw materials according to the proportion of the above coking coal upgrading agent, and then sending the various raw materials into a mixer to stir evenly.

[0031] The method of using the coking coal modifying agent of the present invention: adding and mixing the prepared modifying agent of the present invention through simple equipment before the coking coal is pulverized. After the crushing process, the purpose of mixing evenly can be achieved.

[0032] Embodiment 2: basically the same as Embodiment 1, the difference is:

Embodiment 2

[0033] The coking coal upgrading agent of the present invention is expressed in weight percentage, and the coking coal upgrading agent is made of 40% boric acid as raw materials, 20% antimony oxide and 40% medium temperature modified asphalt.

[0034] Embodiment 3: basically the same as Embodiment 1, the difference is:

Embodiment 3

[0035] The coking coal upgrading agent of the present invention is expressed in weight percentage, and the coking coal upgrading agent is made of 70% of boric acid as raw materials, 10% of antimony oxide and 20% of medium-temperature modified asphalt.

[0036] Embodiment 4: basically the same as Embodiment 1, the difference is:

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PUM

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Abstract

The invention discloses a coking coal modifier. The coking coal modifier mainly comprises the raw materials as follows according to weight percent: 40% to 70% of boric acid, 10% to 20% of antimony oxide and 20% to 40% of moderate-temperature modified asphalt, and the coking coal modifier is prepared by mixing the raw materials. When the coking coal modifier provided by the invention is added during the coking process of coking coal, the reactivity of coke can be reduced effectively, and the strength of reacted coke can be improved; when the coking coal modifier provided by the invention is used during coal injection of coking, the use amount of coking coal, rich coal and other high-quality coking coal can be reduced greatly, the use amount of lean coal, gas coal and other coal with poor caking performance can be increased, even the use amount of non-caking coal can be increased, and high-quality and qualified coke can be obtained, so that the cost of coking can be reduced remarkably. The coking coal modifier provided by the invention can effectively change the molecular structure of coal to achieve the purposes that coke has good coking effect and high coking density and strength, the thermal response of coke can be reduced effectively and the thermal intensity of coke can be improved; and by adoption of the coking coal modifier provided by the invention, the use amount of high-quality coking coal can be reduced, and energy can be saved. Therefore, the coking coal modifier has remarkable economic benefits and social benefits.

Description

technical field [0001] The invention belongs to the field of coal processing, and in particular relates to a coking coal modifying agent for improving coke quality, that is, a coking coal additive. Background technique [0002] With the further increase of blast furnace smelting intensity, and the application of intensified smelting technologies such as large-scale blast furnaces and large coal injection, the requirements for raw materials of blast furnaces have gradually increased, that is, the quality of coke (main indicators are M40, M10, CRI, CSR) has been raised. higher and higher requirements. At present, most of them use high-quality coking coal in a large proportion to achieve the purpose of refining high-quality coke. However, as high-quality coking coal resources become more and more scarce, weak caking coal must be used for coking. For the defects of poor caking performance in weak caking coking coal, although corresponding technological measures (such as tampin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10B57/06C21B5/00
Inventor 曹金贵
Owner 曹金贵
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