Photo-assisted chargeable lithium ion secondary battery

A technology for secondary batteries and rechargeable lithium, applied in secondary batteries, non-aqueous electrolyte battery electrodes, circuits, etc., can solve the problems that chemical energy cannot exist stably for a long time, storage energy is limited, and cost is low, and achieves a high degree of chemical stability. , the effect of increasing energy and reducing the degree of self-discharge

Inactive Publication Date: 2012-08-15
BEIJING INSTITUTE OF TECHNOLOGYGY +1
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Problems solved by technology

[0006] Aiming at the defects in the prior art that the light-assisted charging lithium-ion secondary battery has limited storage energy and the stored chemical energy cannot exist stably for a long time; the purpose of the present invention is to provide a light-assisted charging lithium-ion secondary battery. The photoelectric conversion semiconductor positive electrode material of the photoelectrochemi

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  • Photo-assisted chargeable lithium ion secondary battery
  • Photo-assisted chargeable lithium ion secondary battery

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Embodiment

[0029] A light-assisted rechargeable lithium-ion secondary battery, such as figure 1 As shown, the battery is composed of a positive electrode, a separator 3, a negative electrode, an electrolyte solution, and a wire 6; wherein, the separator 3 is located between the positive electrode and the negative electrode, so that the positive electrode and the negative electrode have a separated structure in space, and between the positive electrode and the negative electrode Connect with wire 6.

[0030] The positive electrode is mainly composed of positive electrode active material 2 titanium dioxide powder and positive electrode current collector 1FTO conductive glass; it is obtained by coating titanium dioxide powder on a 1cm×1cm FTO conductive glass by coating method, and then putting it into a muffle furnace for sintering at 500°C for 1h The thickness of the positive electrode and titanium dioxide powder is 50 μm. Wherein, the titanium dioxide powder is anatase titanium dioxide ...

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Abstract

The invention relates to a photo-assisted chargeable lithium ion secondary battery, belonging to a cross domain of a photo-electro-chemical solar battery and a lithium ion secondary battery. The battery consists of an anode, a diaphragm, a cathode, an electrolyte solution and a lead wire. The diaphragm is located between the anode and the cathode; an external circuit between the anode and the cathode is communicated by using the lead wire; and an internal circuit is communicated by using the electrolyte solution to form a closing loop; the anode is a photo-permeability anode used by the photo-electro-chemical solar battery; the cathode is a cathode used by the lithium ion secondary battery; the diaphragm is an oxidation-resistant diaphragm capable of transmitting lithium ions and iodide ions and not transmitting iodide molecules, and the diaphragm is used by the lithium ion secondary battery; and the electrolyte solution is an organic electrolyte solution used by a lithium ion secondary battery containing Lil and/or LiBr. The battery has great stored energy capacity and solves a self-discharging phenomenon. The stored chemical energy can stably exit. Meanwhile, the charging electric energy consumption can be saved by using low voltage to charge under illumination. The photo-assisted chargeable lithium ion secondary battery provided by the invention has the advantages of low cost, simple equipment and good repeatability.

Description

technical field [0001] The present invention relates to a light-assisted rechargeable lithium-ion secondary battery, in particular to a novel light-assisted rechargeable lithium-ion secondary battery formed by combining photoelectric conversion and secondary battery materials, belonging to photoelectrochemical solar cells and The cross field of lithium ion secondary battery. Background technique [0002] Photoelectrochemical solar cells and lithium-ion secondary batteries have been in large-scale commercial applications for a long time, and the development and research of existing materials are becoming more and more mature. Today, no matter where you are, you cannot do without the application of batteries; in the future when natural reserves such as coal and oil are depleted, electric energy will become the largest source of energy supply. Since the first batch of commercially applicable batteries appeared in research laboratories in the early eighteenth century, the perfo...

Claims

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Application Information

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IPC IPC(8): H01M10/0525H01M10/46H01M4/13
CPCY02E60/10
Inventor 吴锋谢潇怡张存中吴伯荣穆道斌
Owner BEIJING INSTITUTE OF TECHNOLOGYGY
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