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Lithium-ion battery anode pole piece and lithium-ion battery comprising the anode pole piece

A lithium ion battery and pole piece technology, which is applied in the field of lithium ion battery anode pole piece and lithium ion battery including the anode pole piece, can solve the problem of the expansion and release of the anode membrane, the impact of the membrane on the safety and reliability of the battery, Reduce the content of active substances and other problems, achieve high gram capacity and energy density, good electron conduction, and solve the effect of swelling and film removal

Active Publication Date: 2016-08-03
DONGGUAN AMPEREX TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The shedding of the diaphragm seriously affects the safety and reliability of the battery
[0003] For the traditional single-layer diaphragm, the charging expansion and release of silicon anode materials and alloy anode materials have not been solved. In order to solve this problem, we can greatly increase the binder content in the diaphragm to strengthen the diaphragm and set The bonding strength between the fluids is to resist the stress generated at the interface between the diaphragm layer and the current collector due to the expansion of the diaphragm layer during charging, but increasing the binder content will lead to a decrease in the active material content in the diaphragm and Reduction of diaphragm dynamics
[0004] In view of this, it is indeed necessary to provide a lithium-ion battery anode pole piece, which can solve the problem of swelling and defilming of the anode membrane that is prone to occur during the charging process of the battery without affecting the kinetic performance of the battery. Improve battery safety and reliability while achieving high battery capacity

Method used

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  • Lithium-ion battery anode pole piece and lithium-ion battery comprising the anode pole piece

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Embodiment 1: as figure 1 As shown, the anode sheet of a lithium ion battery provided in this embodiment includes a current collector 1 , a first coating 2 disposed on the surface of the current collector 1 , and a second coating 3 disposed on the surface of the first coating 2 . Wherein, the active substance in the second coating 3 is graphite, and the thickness of the second coating 3 is 20 μm; The ratio of the orthographic projection area is 1 (wherein, the orthographic projection area refers to the orthographic projection area of ​​the plane where the length and width of the current collector 1 and the first coating 2 are located). And the first coating 2 is a composite material layer, and the composite material layer is composed of styrene-butadiene rubber and carbon powder, wherein the mass percentage of carbon powder to the total mass of the first coating is 90%.

[0024]During preparation, first disperse styrene-butadiene rubber into N-methylpyrrolidone to obta...

Embodiment 2

[0025] Embodiment 2: as figure 1 As shown, the anode sheet of a lithium ion battery provided in this embodiment includes a current collector 1 , a first coating 2 disposed on the surface of the current collector 1 , and a second coating 3 disposed on the surface of the first coating 2 . Wherein, the active material in the second coating 3 is a mixture of graphite and silicon (the mass ratio of the two is 7:3), and the thickness of the second coating 3 is 100 μm; the first coating 2 is a discontinuous coating layer, which includes several coating blocks distributed on the surface of the current collector 1, and the ratio of the sum of the orthographic projection areas of each coating block to the orthographic projection area of ​​the current collector 1 is 0.5:1. The thickness of the first coating 2 is 1 μm, and the first coating 2 is a composite material layer, and the composite material layer is composed of polyvinylidene fluoride and carbon nanotubes, wherein the mass percen...

Embodiment 3

[0027] Embodiment 3: as figure 1 As shown, the anode sheet of a lithium ion battery provided in this embodiment includes a current collector 1 , a first coating 2 disposed on the surface of the current collector 1 , and a second coating 3 disposed on the surface of the first coating 2 . Wherein, the active material in the second coating 3 is a tin-carbon alloy, and the thickness of the second coating 3 is 50 μm; the first coating 2 is a discontinuous coating, which includes several smear blocks, and the ratio of the sum of the orthographic projection areas of each smear block to the orthographic projection area of ​​the current collector 1 is 0.6:1. The thickness of the first coating 2 is 3 μm, and the first coating 2 is a composite material layer, and the composite material layer is composed of sodium carboxymethyl cellulose and vapor-phase grown carbon fibers, wherein the vapor-phase grown carbon fibers account for a mass of the total mass of the first coating The percentag...

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Abstract

The invention belongs to the technical field of a lithium ion battery and particularly relates to a lithium ion battery anode pole piece. The lithium ion battery anode pole piece comprises a current collector, a first coating and a second coating, wherein the first coating is arranged on the surface of the current collector; the second coating is arranged on the surface of the first coating; the second coating comprises active materials; the active materials are at least one of graphite, silicon, silicon alloy and tin alloy; the first coating is a composite layer comprising an adhesive and a conductive additive; and the thickness of the first coating is 0.1mum to 5mum. The invention can solve the problem of stripping of a high gram volume anode membrane in the charging and discharging process without increasing the content of the adhesive in the anode membrane and can effectively prevent the expansion and stripping of the anode membrane in the repeated charging and discharging process of the battery on the premise of not influencing the dynamics performance of the battery, so that the safety and the reliability of the battery are improved when the high volume and the high energy density of the battery are implemented. Moreover, the invention also discloses a lithium ion battery comprising the anode pole piece.

Description

technical field [0001] The invention belongs to the technical field of lithium ion batteries, and in particular relates to an anode pole piece of a lithium ion battery and a lithium ion battery including the anode pole piece. Background technique [0002] Lithium-ion batteries are widely used in various consumer electronics products, various electric vehicles, and energy storage devices such as wind energy and solar energy because of their high energy density, long cycle life, excellent mechanical properties, and environmental friendliness. In recent years, people have higher and higher requirements for the energy density of batteries, which requires the anode materials used to have higher and higher gram capacities. Among various anode materials, graphite materials and silicon alloys have higher gram capacity. However, the anode material with a high gram capacity also brings about a large expansion problem during charging and cycling, and causes serious film removal proble...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/13H01M10/0525
CPCY02E60/10
Inventor 李白清张盛武陶泽天李吉蓉宋学文张柏清
Owner DONGGUAN AMPEREX TECH
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