A temperature-sensitive slow-release gas-phase fresh-keeping composite film for baked food and its preparation method
A baked food and temperature-sensitive technology, which is applied in the field of temperature-sensitive slow-release gas-phase fresh-keeping composite film and its preparation, can solve the problems of restricting baked food, unsatisfactory anti-corrosion and fresh-keeping effects, and strict hygienic conditions, so as to achieve extended shelf life and good quality. Fresh-keeping effect, effect of inhibiting microbial growth
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Embodiment 1
[0029] 1mol of polycaprolactone (PCL, Mw=3000), 2mol of 4,4'-diphenylmethane diisocyanate (MDI), 700g of N,N-dimethylformamide (DMF) solvent, react at 70°C 1.5h, the formation of soft segment phase. Then add metered BDO and MDI and react at 70°C for 1.5h to form hard segments, and the soft and hard segments alternately form block polymers; during the reaction, keep the molar ratio of -NCO and -OH groups at 1:1, use DMF regulates the viscosity change in the reaction system, and the solid content of the temperature-sensitive polyurethane solution is controlled at 25wt%. Further use DMF to adjust the solid content to be 15wt%, place it on the polytetrafluoroethylene template, and evaporate the DMF solvent at 60°C to obtain a temperature-sensitive polyurethane film. On the obtained polyurethane film, brush for Antibacterial agent (carvacrol) with 2% film weight, the treated polyurethane film and nylon are bonded with a hot press at a temperature of 90°C, a pressure of 0.2MPa, and...
Embodiment 2
[0031] 2mol polycaprolactone (PCL, Mw=4000), 3.5mol4,4'-diphenylmethane diisocyanate (MDI), 1200g of N,N-dimethylformamide (DMF) solvent, at 75°C After 1 hour of reaction, a soft segment phase was formed. Then add metered BDO and MDI and react at 80°C for 1.5h to form hard segments, and the soft and hard segments alternately form block polymers; during the reaction, keep the molar ratio of -NCO and -OH groups at 1:1, use DMF regulates the viscosity change in the reaction system, and the solid content of the temperature-sensitive polyurethane solution is controlled at 45wt%. Further use DMF to adjust the solid content to be 25wt%, place it on the polytetrafluoroethylene template, and evaporate the DMF solvent at 75°C to obtain a temperature-sensitive polyurethane film. On the obtained polyurethane film, brush for Antibacterial agent (cinnamaldehyde) with 2% film weight, the treated polyurethane film and nylon are bonded with a hot press at a temperature of 90°C, a pressure of ...
Embodiment 3
[0033]0.2mol polycaprolactone (PCL, Mw=8000), 0.5mol4,4'-diphenylmethane diisocyanate (MDI), 400g of N,N-dimethylformamide (DMF) solvent, at 80°C Under reaction for 2h, a soft segment phase is formed. Then add metered BDO and MDI and react at 80°C for 2 hours to form hard segments, and the soft and hard segments alternately form block polymers; during the reaction, keep the molar ratio of -NCO and -OH groups at 1:1, use DMF Adjust the viscosity change in the reaction system, and control the solid content of the temperature-sensitive polyurethane solution to 30wt%. Further use DMF to adjust the solid content to 20wt%, place it on a polytetrafluoroethylene template, and evaporate the DMF solvent at 70°C to obtain a temperature-sensitive polyurethane film. agent (1% carvacrol + 1% cinnamaldehyde), the treated polyurethane film and nylon are bonded with a hot press at a temperature of 120°C, a pressure of 0.1MPa, and a time of 2s to obtain a temperature-sensitive anti-corrosion ...
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