A ceramicized
composite material, its preparation method, and its application, comprising, by weight: 100 parts of
silicone rubber matrix; 50-120 parts of
ceramic-forming filler
system; 10-40 parts of
active fire extinguishing microcapsules; 5-20 parts of sacrificial template agent; and 2-10 parts of synergistic additives. The
ceramic-forming filler
system, by weight, comprises: 30-60 parts of synthetic fluorophlogopite
powder; 15-40 parts of low-melting-point glass
powder; and 5-20 parts of reinforcing skeleton filler. The core material of the
active fire extinguishing microcapsules is perfluorohexanone; the
wall material of the
active fire extinguishing microcapsules has a double-layer structure, with an inner layer of
melamine resin and an outer layer of
polyurea or silica grafted with vinyl groups. The sacrificial template agent is a core-shell structured
thermoplastic expandable microsphere, with a core material of liquid
alkane and a shell material of a
copolymer of vinylidene
chloride,
acrylonitrile, and
methyl methacrylate; the expansion temperature of the sacrificial template agent is 180°C-220°C, and its
pyrolysis temperature is 300°C-400°C. This invention has the advantages of active
flame suppression, ultra-low
thermal conductivity, and robust structure.