Catalyst regeneration method capable of reducing carbon dioxide discharge and improving selectivity

A carbon dioxide and catalyst technology, which is applied in the regeneration field of carbon-containing catalysts, can solve problems such as high coke and dry gas yields, achieve the effects of reducing coke and dry gas yields, reducing floor space, and improving use efficiency

Active Publication Date: 2014-04-16
CHINA PETROLEUM & CHEM CORP +1
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Problems solved by technology

For example, the highest activity recovery of the regenerated catalyst can be achieved during regeneration, but when the regenerated catalyst participates in the reaction, it may cause high coke and dry gas yields due to its high activity, which is undesirable

Method used

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  • Catalyst regeneration method capable of reducing carbon dioxide discharge and improving selectivity

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Embodiment

[0035] The embodiment is carried out on a catalytic cracking demonstration unit, as shown in the accompanying drawing. The demonstration plant does not have a flue gas energy recovery system and a carbon dioxide separation system. The inner diameter of the dense-phase bed of the first regenerator is 50 cm, and the inner diameter of the dense-phase bed of the second regenerator is 40 cm. The catalyst is regenerated according to the regeneration method proposed by the present invention, and pure oxygen gas is introduced into the dense-phase beds of the first regenerator and the second regenerator respectively, and at the same time, the flue gas part from the cyclone separation system of the first regenerator is returned to the second regenerator. At the bottom of the dense-phase bed of the second regenerator, the other part merges with the flue gas from the second regenerator and exits the demonstration device. The bed temperature of the first regenerator is 640°C, and the dens...

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Abstract

The invention discloses a catalyst regeneration method capable of reducing carbon dioxide discharge and improving selectivity. The catalyst regeneration method is characterized in that a catalyst with coke is subjected to pure oxygen-based partial regeneration in a first regenerator, and the partially regenerated catalyst goes through a lifting pipe, then is fed into a second regenerator above the first regenerator and then is subjected to pure oxygen-based residual coke burning; flue gas discharged from the first regenerator is divided into two parts, one of the two parts is circularly supplied to the bottom of the second regenerator and the other part of the two parts is fed into a flue gas energy recovery system; flue gas discharged from the second regenerator and the first regenerator flue gas discharged from the flue gas energy recovery system are mixed and the mixed flue gas is fed into a carbon dioxide separation system; after carbon dioxide separation, a capturing process is carried out; and the regenerated catalyst is cooled and activated and then is fed into a reactor for recycle. The catalyst regeneration method realizes complete regeneration of a catalyst and uniform distribution of catalyst activity so that coke as a catalytic cracking by-product and a dry gas yield are reduced. The catalyst regeneration method greatly reduces carbon emission and even realizes zero emission of carbon.

Description

technical field [0001] The invention relates to a method for regenerating carbon-containing catalysts in hydrocarbon processing. More specifically, the present invention relates to a catalyst regeneration method for reducing carbon dioxide emissions and improving catalyst selectivity in the heavy oil catalytic cracking process. Background technique [0002] Today, the development of the global oil refining industry is facing many challenges such as oil price fluctuations, the trend of worsening crude oil quality, improved oil product quality specifications, stricter requirements for energy conservation and emission reduction, and the rapid development of biofuels. Reducing carbon dioxide emissions and mitigating climate change have become the key factors for the oil refining industry to transform the economy. The way of growth and the only way to maintain sustainable development. In October 2009, the country announced the action goal of controlling greenhouse gas emissions,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J38/34B01J29/90
Inventor 王新许友好龚剑洪崔守业
Owner CHINA PETROLEUM & CHEM CORP
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